205582-30-5Relevant academic research and scientific papers
Tunable stereoselective alkene synthesis by treatment of activated imines with nonstabilized phosphonium ylides
Dong, De-Jun,Li, Yuan,Wang, Jie-Qi,Tian, Shi-Kai
supporting information; experimental part, p. 2158 - 2160 (2011/03/20)
A broad range of readily accessible N-sulfonyl imines undergo olefination reaction with nonstabilized phosphonium ylides under mild conditions to afford an array of both Z- and E-isomers of 1,2-disubstituted alkenes, allylic alcohols, and allylic amines in good yields and with greater than 991 stereoselectivity.
Synthesis of unsaturated organotrifluoroborates via Wittig and Horner-Wadsworth-Emmons olefination
Molander, Gary A.,Figueroa, Ruth
, p. 6135 - 6140 (2007/10/03)
The stereoselective synthesis of unsaturated organotrifluoroborates by using the Wittig and Horner-Wadsworth-Emmons olefination is described. These reactions were general for both alkyl- and aryltrifluoroborates. The synthesis of di- and trisubstituted ol
