93039-03-3

Basic information

• Product Name: (2E,4E)-N,N-dimethyl-5-phenylpenta-2,4-dien-1-amine
• Synonyms: (2E,4E)-N,N-dimethyl-5-phenylpenta-2,4-dien-1-amine
• CAS NO: 93039-03-3
• Molecular Weight: 187.285
• Mol File: 93039-03-3.mol

Chemical Properties

• CAS DataBase Reference: (2E,4E)-N,N-dimethyl-5-phenylpenta-2,4-dien-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,4E)-N,N-dimethyl-5-phenylpenta-2,4-dien-1-amine(93039-03-3)
• EPA Substance Registry System: (2E,4E)-N,N-dimethyl-5-phenylpenta-2,4-dien-1-amine(93039-03-3)

Safety Data

• Hazardous Substances Data: 93039-03-3(Hazardous Substances Data)

Upstream product

• 205582-30-5 [(dimethylamino)ethyl]triphenylphosphonium bromide 
• 109529-98-8 ((1E,3E)-5-bromopenta-1,3-dien-1-yl)benzene 
• 124-40-3 dimethyl amine 
• 58506-33-5 5-phenyl-trans,trans-2,4-pentadien-1-ol 
• 14371-10-9 (E)-3-phenylpropenal 
• 39806-16-1 ethyl (2E,4E)-5-phenyl-penta-2,4-dienoate 

Downstream Products

• 1581720-36-6 (2S,3S,E)-N-benzyl-2-(dimethylamino)-5-phenyl-3-vinylpent-4-enamide 

Relevant articles and documents

An isothiourea-catalyzed asymmetric [2,3]-rearrangement of allylic ammonium ylides

Benzotetramisole promotes the catalytic asymmetric [2,3]-rearrangement of allylic quaternary ammonium salts (either isolated or prepared in situ from p-nitrophenyl bromoacetate and the corresponding allylic amine), generating syn-α-amino acid derivatives with excellent diastereo- and enantioselectivity (up to >95:5 dr; up to >99% ee).

Tunable stereoselective alkene synthesis by treatment of activated imines with nonstabilized phosphonium ylides

A broad range of readily accessible N-sulfonyl imines undergo olefination reaction with nonstabilized phosphonium ylides under mild conditions to afford an array of both Z- and E-isomers of 1,2-disubstituted alkenes, allylic alcohols, and allylic amines in good yields and with greater than 991 stereoselectivity.