20566-49-8

Upstream product

• 123726-16-9 bis(4-methylphenyl)iodonium trifluoromethanesulfonate 
• 132627-71-5 2-[(4-methylphenylsulfonyl)methyl]propenoic acid ethyl ester 
• 60565-88-0 bis(4-methylphenyl)iodonium hexafluorophosphate 
• 80787-04-8 ethyl 2-(acetoxymethyl)acrylate 
• 5142-75-6 tri(p-tolyl)bismuth 
• 17435-72-2 ethyl 2-bromomethyl-2-propenoate 

Downstream Products

• 107673-39-2 2-(4-Methyl-benzyl)-acrylic acid 
• 111510-56-6 Thiobenzoic acid S-(2-chlorocarbonyl-3-p-tolyl-propyl) ester 
• 111510-45-3 2-Benzoylsulfanylmethyl-3-p-tolyl-propionic acid 

Relevant academic research and scientific papers

Aryl radical formation by copper(I) photocatalyzed reduction of diaryliodonium salts: NMR Evidence for a CuII/CuI mechanism

Photocatalyzed reduction of diaryliodonium salts was achieved by using [Cu(dpp)2][PF6] as a photoactive complex and DIPEA as a reductive quench. The application of a copper catalyst allows the generation of aryl radicals under mild conditions and maintains their reactivity for C-C bond formation processes.

Pd-catalyzed threefold arylation of Baylis-Hillman bromides and acetates with triarylbismuth reagents

Functionalized alkyl 2-benzylacrylates and 2-benzylacrylonitriles were synthesized by means of atom-economic cross-couplings of Baylis-Hillman bromides or acetates with BiAr3 under palladium-catalyzed conditions. These reactions, involving thre