2060-89-1Relevant articles and documents
Theory and practice: Bulk synthesis of C3B and its H2- and Li-storage capacity
King, Timothy C.,Matthews, Peter D.,Glass, Hugh,Cormack, Jonathan A.,Holgado, Juan Pedro,Leskes, Michal,Griffin, John M.,Scherman, Oren A.,Barker, Paul D.,Grey, Clare P.,Dutton, Sian E.,Lambert, Richard M.,Tustin, Gary,Alavi, Ali,Wright, Dominic S.
supporting information, p. 5919 - 5923 (2015/05/13)
Previous theoretical studies of C3B have suggested that boron-doped graphite is a promising H2- and Li-storage material, with large maximum capacities. These characteristics could lead to exciting applications as a lightweight H
Retinobenzoic Acids. 5. Retinoidal Activities of Compounds Having a Trimethylsilyl or Trimethylgermyl Group(s) in Human Promyelocytic Leukemia Cells HL-60
Yamakawa, Takeru,Kagechika, Hiroyuki,Kawachi, Emiko,Hashimoto, Yuichi,Shudo, Koichi
, p. 1430 - 1437 (2007/10/02)
The retinoidal activities of trimethylsilyl or trimethylgermyl-containing retinobenzoic acids are discussed on the basis of differentiation-inducing activity on human promyelocytic leukemia cells HL-60.Compounds with a trimethylsilyl or trimethylgermyl gr
ELECTRON SPIN RESONANCE AND CHEMICAL STUDIES ON THE 6-(TRIMETHYLSILYL)CYCLOHEXADIENYL AND RELATED RADICALS.
Kira,Sugiyama,Sakurai
, p. 6436 - 6442 (2007/10/02)
Various 3,6-disubstituted cyclohexadienyl radicals were generated and investigated by ESR at low temperature. Analysis of the ESR parameters indicated that the significant out-of-plane deformation of the carbon framework of 6-Me//3Si- and 6-Me//3Ge-substituted cyclohexadienyl radicals occurred to gain stabilization due to the effective hyperconjugation between the substituted methylene pseudo- pi orbital and the pi SOMO, while the 6-unsubstituted and 6-t-Bu cyclohexadienyl radicals were essentially planar. Investigation of the fate of the 3,6-bis(trimethylsilyl)cyclohexadienyl radical showed strong evidence for the temperature-dependent reversibility of the silyl radical addition to aromatics. The spontaneous elimination of the trimethylsilyl radical was proved by spin-trapping experiments.