17983-62-9

Basic information

• Product Name: Ethanone, 1-[3-(trimethylsilyl)phenyl]-
• CAS NO: 17983-62-9
• Molecular Formula: C11H16OSi
• Molecular Weight: 192.333
• Mol File: 17983-62-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[3-(trimethylsilyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[3-(trimethylsilyl)phenyl]-(17983-62-9)
• EPA Substance Registry System: Ethanone, 1-[3-(trimethylsilyl)phenyl]-(17983-62-9)

Safety Data

• Hazardous Substances Data: 17983-62-9(Hazardous Substances Data)

Upstream product

• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 2142-63-4 1-(3-Bromophenyl)ethanone 
• 2060-89-1 m-bis(trimethylsilyl)benzene 
• 75-36-5 acetyl chloride 
• 5624-60-2 1,3,5-tris(trimethylsilyl)benzene 
• 39172-32-2 2-(3-bromophenyl)-2-methyl-[1,3]dioxolane 
• 50882-51-4 1-(3-Trimethylsilylphenyl)ethylalkohol 
• 52780-14-0 1-(3-bromophenyl)ethanol 
• 75-77-4 chloro-trimethyl-silane 
• 2725-82-8 1-bromo-3-ethylbenzene 
• 541-73-1 1,3-Dichlorobenzene 
• 626-39-1 1,3,5-trisbromobenzene 
• 155734-85-3 2-methyl-2-<3'-(trimethylsilyl)phenyl>-1,3-dioxolane 
• 17988-51-1 1-Ethyl-3-trimethylsilylbenzol 

Downstream Products

• 151774-87-7 ethyl (E)-3-<3'-(trimethylsilyl)phenyl>-2-butenoate 
• 125973-57-1 (E)-4-<3-oxo-3-<3-(trimethylsilyl)phenyl>-1-propenyl>benzoic acid 
• 1415605-85-4 3-(3-acetylphenyl)-1-benzothiophene 
• 1415605-82-1 2-(3-acetylphenyl)benzo[b]thiophene 
• 151957-63-0 (2R,3S)-3-(3'-iodophenyl)butane-1,2-diol 
• 151774-89-9 (E)-3-<3'-(trimethylsilyl)phenyl>-2-buten-1-ol 
• 22161-82-6 (+)-α-(3-benzylphenyl)propionic acid 
• 151957-59-4 (S)-2-(3'-iodophenyl)propanoic acid 
• 173436-86-7 (RS)-2-(3'-iodophenyl)propanoic acid 

Relevant articles and documents

Application of a promiscuous Arthrobacter sp. from Antarctic in aerobic (R)-selective deracemization and anaerobic (S)-selective reduction

Inspired by enzyme-catalyzed reactions with microorganisms found in harsh marine environments, in which the amount of oxygen is restrict, we have shown that Arthrobacter sp. can perform different chemical transformations by switching from anaerobic to aerobic reaction conditions. Depending on the presence or absence of oxygen, either alcohol deracemization or ketone reduction with enantiocomplementary selectivities can be performed by the same microorganism. For example, reactions performed in the presence of oxygen favored the deracemization process, in which a racemic mixture of 1-(4-methylphenyl)ethanol was enriched to the (R)-alcohol in high conversion (94%) and high enantiomeric excess (94%). On the other hand, reaction in the absence of oxygen favored the reduction process, in which 4-methyl-acetophenone was converted to the (S)-alcohol in good conversion (58%) and excellent enantiomeric excess (>99%). These concepts were applied for both deracemization and enantioselective reduction of heteroatom-containing (silicon, phosphorus, tin and boron) molecules. Moreover, preparative scale reactions were also performed for both chemical processes.

Heterocyclic dihydrazole compounds and their use for controlling fungal plant diseases

PCT No. PCT/US96/06533 Sec. 371 Date Nov. 13, 1997 Sec. 102(e) Date Nov. 13, 1997 PCT Filed May 8, 1996 PCT Pub. No. WO96/36633 PCT Pub. Date Nov. 21, 1996Compounds of Formula I, and their N-oxides and agriculturally suitable salts, are disclosed which ar

Synthese d'aryl- et heteroarylsilanes par scission de l'hexamethyldisilane

In the presence of hexamethylphosphormaide and a catalytic quantity of tetrakis(triphenylphosphine)palladium, hexamethyldisilane reacts with various functional aryl bromides to give the corresponding arylsilanes in satisfactory yields.The reaction has bee