20682-70-6Relevant articles and documents
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Schostakowskii
, p. 608,616, engl. Ausg. S. 643, 651 (1950)
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Electrophilic Addition to Alkoxyethenes. XVI. Influence of Reagent Structure and Solvent on the Rate of Addition of Alcohols to Butyl Vinyl Ether
Nedolya, N. A.,Baranskii, V. A.,Trofimov, B. A.
, p. 291 - 295 (2007/10/03)
The influence of solvent and the structure of alcohol on the rate of its acid-catalyzed (HCl) addition to butyl vinyl ether was studied at 25 deg C in a mixture of the reacting alcohol with a solvent (1:4 by volume).The electrophilic attack of the substrate by solvated proton in the rate-determining stage is accompanied and facilitated by the simultaneous attack of the alkoxide ion on the resulting carboxonium center, i.e., the alcohol molecule participates in formation of the transition state.