206983-87-1

Upstream product

• 206983-88-2 1,2,3-O-tribenzyl-D-threitol 
• 113350-84-8 (2R,3R)-(-)-2,3-bis(phenylmethoxy)-1,4-butanediol 
• 100-39-0 benzyl bromide 

Downstream Products

• 206983-89-3 3,4,5-O-tribenzyl-1-deoxy-D-xylulose 
• 637775-76-9 C₂₅⁽¹³⁾CH₂₈O₄ 
• 637775-73-6 2,3,4-tris-benzyloxy-N-methoxy-N-methyl-butyramide 

Relevant academic research and scientific papers

METHOD FOR PRODUCING [1-13C]1-DEOXY-D-XYLULOSE

PROBLEM TO BE SOLVED: To provide a method for producing a [1-13C]DOX (1-deoxy-D-xylulose) synthesizable in a large amount and to obtain a DOX derivative that is stable and efficiently taken by a cell. SOLUTION: The [1-13C]DOX represe

A practical access to [1-13c]1-deoxy-d-xylulose and its derivatives

A practical synthesis of [1-13C]1-deoxy-D-xylulose and its triacetate and 5-phosphate derivatives is described. The present scheme is developed based on the consideration of the cost efficiency of 13C.

New and efficient synthetic routes to 1-deoxy-D-xylulose

The biochemically important deoxysugar 1-deoxy-D-xylulose was synthesized by improved methods. D-Tartaric acid is the starting material for a synthesis which proceeds via the intermediacy of 2,3,4-tribenzyl-D- threitol. Another, highly efficient route use, the Sharpless asymmetric dihydroxylation of 5-benzyloxy-3-penten-2-one as its key step. These syntheses are especially useful-for isotopic labelling.