207223-47-0Relevant academic research and scientific papers
Synthesis and crystal structure of a bis(phosphiren-1-yl)-iron complex
Simon,Bergstraesser,Regitz
, p. 867 - 868 (1998)
1-Chloro-1H-phosphirenes 5 react with disodium tetracarbonylferrate to furnish the novel mono-complexed bis(phosphirenyl)s 7 which, in turn, are converted to the doubly-complexed species 8 by treatment with nonacarbonyldiiron.
Synthesis and reactions of (1,1′-bi-1H-phosphirene)iron complexes - Crystal structure of a bridged (1-phosphaallyl-1H-phosphirene)diiron(Fe-Fe) complex
Simon, Juergen,Reiss, Guido J.,Bergstraesser, Uwe,Heydt, Heinrich,Regitz, Manfred
, p. 2067 - 2073 (2007/10/03)
The reactions of 1-chloro-1H-phosphirenes 5 with disodium tetracarbonlyferrate lead to the selective formation of the mono complexed bi-1H-phosphirenes 7, which are converted into the doubly complexed species 9 upon treatment with diiron nonacarbonyl. Photochemical opening of one of the two three-membered ring systems in 9 furnishes the bridged complexes 10 containing phosphirene and phosphaallyl units together with an iron-iron σ-bond.
