207994-96-5Relevant academic research and scientific papers
Indium-employed one-pot sequential double nucleophilic attack on a symmetrical dicarboxaldehyde
Babu, Srinivasarao Arulananda,Yasuda, Makoto,Shibata, Ikuya,Baba, Akio
, p. 1223 - 1226 (2004)
A novel concept of one-pot sequential double nucleophilic attacks using two different nucleophiles to a molecule having identical functionalities was established via an indium-employed allylation strategy involving an HOAc quenching after the first allylation.
Rhodium-catalyzed reductive allylation of conjugated aldehydes with allyl acetate
Vasylyev, Maksym,Alper, Howard
supporting information; experimental part, p. 2710 - 2713 (2010/07/17)
Reductive allylation of aryl and alkenyl aldehydes with allyl acetate catalyzed by the ionic diamine carbonyl rhodium complex, [Rh(TMEDA)(CO) 2][RhCl2(CO)2], under a carbon monoxide atmosphere afforded the corresponding homoallylic alcohols in good isolated yields.
Ruthenium-catalyzed isomerization of homoallylic alcohols in water
Wang, Dong,Chen, Dongli,Haberman, John X.,Li, Chao-Jun
, p. 5129 - 5142 (2007/10/03)
Through the catalysis of RuCl2(PPh3)3, the functional groups of homoallylic alcohols are repositioned to give allylic alcohols with controlled regioselectivity. The reaction proceeds most efficiently in an aqueous media. The selectivity in product formation is affected by the reaction temperature and the amount of the catalyst being used. A higher reaction temperature and the use of a smaller amount of the catalyst are preferable for the formation of allylic alcohols. The reaction process was postulated as a tandem olefin migration-allylic rearrangement. Under the same reaction conditions, the functional groups of allylic alcohols undergo allylic rearrangements.
