Improved Synthesis of the C8-C23 Segment of Aplysiatoxins via Asymmetric Dihydroxylation of the Chiral Homoallylic Alcohol

DOI: 10.1271/bbb.62.599

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Bioscience, Biotechnology and Biochemistry p. 599 - 602 (1998)

Update date:2022-08-05

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Authors:

Toshima, Hiroaki

Ichihara, Akitami

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Article abstract of DOI:10.1271/bbb.62.599

Important intermediate 2 of the segment (3) possessing four sequential asymmetric centers (C9-C12) of aplysiatoxins was synthesized via dihydroxylation of 5 in only 7 steps from methyl (S)-3-hydroxy-2-methylpropionate.Another promising compound (10a) was

Full text of DOI:10.1271/bbb.62.599

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