208333-33-9

Basic information

• Product Name: Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)]BF₄
• CAS NO: 208333-33-9
• Molecular Weight: 623.361
• Mol File: 208333-33-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)]BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)]BF₄(208333-33-9)
• EPA Substance Registry System: Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)]BF₄(208333-33-9)

Safety Data

• Hazardous Substances Data: 208333-33-9(Hazardous Substances Data)

Upstream product

• 14104-20-2 silver tetrafluoroborate 
• 208333-25-9 [(1,10-phenanthroline)PtI(C₆H₅)] 
• 187737-37-7 propene 

Relevant articles and documents

Regiochemical control of a Pt-promoted alkylation of the phenyl ring

The reactivity of cationic PtII-phenyl complexes of the type [PtPh(CH2=CHR)(Phen)]+ (R = H or Me) has been investigated. In all cases, insertion of the alkene into the Pt-Ph bond has been observed. The fate of the resulting Pt-CH2CHRPh (R = H or Me) derivative depends on the experimental conditions. In the presence of donor ligands (e.g. excess olefin, pyridine or triphenylphosphine) the product is stable, while in the absence of them a rapid rearrangement to form Pt-C6H4(CHRMe)-2 occurs.