208333-61-3

Upstream product

• 85716-44-5 methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside 
• 75-09-2 dichloromethane 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 

Downstream Products

• 270924-40-8 carba-5a methyl 2,3,4-tri-O-benzyl-6-deoxy-α-D-xylo-hex-5-enopyranoside 
• 270924-41-9 carba-5a methyl 2,3,4-tri-O-benzyl-β-L-idopyranoside 

Relevant academic research and scientific papers

Titanium (IV) promoted rearrangement of 6-deoxy-hex-5-enopyranosides into cyclohexanones

The Lewis acid Ti(O(i)Pr)Cl3 was found to mediate under very mild conditions (-78 °C) the high-yielding (82-98%) rearrangement of benzylated 6-deoxy-hex-5-enopyranosides of the α-D-gluco, galacto and manno series into substituted cyclohexanones

Conformational Plasticity in Glycomimetics: Fluorocarbamethyl- L -idopyranosides Mimic the Intrinsic Dynamic Behaviour of Natural Idose Rings

Sugar function, structure and dynamics are intricately correlated. Ring flexibility is intrinsically related to biological activity; actually plasticity in L-iduronic rings modulates their interactions with biological receptors. However, the access to the