Titanium (IV) promoted rearrangement of 6-deoxy-hex-5-enopyranosides into cyclohexanones

DOI: 10.1016/S0040-4039(98)00529-2

Source and publish data:

Tetrahedron Letters p. 3471 - 3472 (1998)

Update date:2022-08-12

Topics:

Authors:

Sollogoub, Matthieu

Mallet, Jean-Maurice

Sinay, Pierre

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Article abstract of DOI:10.1016/S0040-4039(98)00529-2

The Lewis acid Ti(O(i)Pr)Cl₃ was found to mediate under very mild conditions (-78 °C) the high-yielding (82-98%) rearrangement of benzylated 6-deoxy-hex-5-enopyranosides of the α-D-gluco, galacto and manno series into substituted cyclohexanones

Full text of DOI:10.1016/S0040-4039(98)00529-2

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