20893-01-0

Usage

Uses

Used in Agricultural Industry:
Acetamiprid is used as an insecticide for controlling a wide range of pests, such as aphids, leafhoppers, thrips, and whiteflies. Its application reason is based on its ability to disrupt the nervous system of insects, leading to paralysis and eventual death. This makes it a preferred choice for protecting various crops, including fruits, vegetables, and ornamentals.
However, it is important to note that Acetamiprid has raised concerns about its potential impact on non-target organisms, particularly pollinators like bees. As a result, its use and application methods may be subject to regulations and restrictions to minimize harm to the environment and beneficial species.

InChI:InChI=1/C10H7N3O3S/c1-8-2-4-10(5-3-8)17(14,15)16-13-9(6-11)7-12/h2-5H,1H3

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 109-77-3 malononitrile 
• 36568-05-5 2-(hydroxyimino)malononitrile 
• 19166-62-2 malononitrile oxime ether sodium salt 

Downstream Products

• 56176-70-6 (2-morpholin-4-yl-2-phenyl-vinylimino)-malononitrile 
• 49845-13-8 (morpholino-2-cyclohexene-1-ylimino)malononitrile 
• 117615-67-5 Toluene-4-sulfonic acid (1S,6S)-2,2-dicyano-6-ethoxy-5-methyl-3,6-dihydro-2H-pyridin-1-yl ester 
• 157224-90-3 2-amino-3-carboxy-5-cyano-6-methoxypyrazine 
• 63062-87-3 (2-methyl-2H-[1,2,3]triazol-4-yl)-(toluene-4-sulfonyloxyimino)-acetonitrile 
• 63062-86-2 (2-methyl-2H-[1,2,3]triazol-4-yl)-(toluene-4-sulfonyloxyimino)-acetonitrile 
• 37144-65-3 1,3-dioxolan-2-one O-p-tosyloxime 
• 33534-26-8 Toluene-4-sulfonic acid (2R,4S)-7,7-dicyano-1-aza-bicyclo[2.2.1]hept-5-en-2-yl ester 
• 907186-46-3 [[2-(2,4-difluorophenyl)-1-methyl-2-(4-morpholinyl)ethenyl]-imino]propanedinitrile 
• 98498-84-1 1-(4-carbethoxyphenyl)-3-(2,2-dicyanomethyleneimino)-4-(1-pyrrolidino)-1,2,5,6-tetrahydropyridine 
• 117615-72-2 Toluene-4-sulfonic acid (1S,6S)-2,2-dicyano-6-ethoxy-5-pentyl-3,6-dihydro-2H-pyridin-1-yl ester 
• 117615-71-1 Toluene-4-sulfonic acid (1S,6S)-5-butyl-2,2-dicyano-6-ethoxy-3,6-dihydro-2H-pyridin-1-yl ester 
• 117615-70-0 Toluene-4-sulfonic acid (1S,6S)-2,2-dicyano-6-ethoxy-5-propyl-3,6-dihydro-2H-pyridin-1-yl ester 
• 117615-69-7 Toluene-4-sulfonic acid (1S,6S)-2,2-dicyano-6-ethoxy-5-isopropyl-3,6-dihydro-2H-pyridin-1-yl ester 

Relevant academic research and scientific papers

PROCESS FOR MANUFACTURING ALKYL 7-AMINO-5-METHYL- [1,2,5]OXADIAZOLO[3,4-B]PYRIDINE-CARBOXYLATE

This invention relates to a novel process for making alkyl 7-amino-5-methyl-[1,2,5]-oxadiazolo[3,4-b]pyridine-carboxylate.

Synthesis of primary amines and N-methylamines by the electrophilic amination of Grignard reagents with 2-imidazolidinone O-sulfonyloxime

2-Imidazolidinone O-sulfonyloxime reacts with various aryl and alkyl Grignard reagents as an electrophilic amination reagent, giving N-alkylated imines. The resulting imines are transformed to primary amines and N-methyl secondary amines by hydrolysis with CsOH and LiAlH4 reduction, respectively.

Evolution thermique et photochimique des triazolines resultant de l'addition des diazocomposes aux esters d'oximino-malonodinitriles, oximino-cyanoacetates et oximino-malonates de methyle

Thermolysis of 1,2,3-triazolines 4,5,6 leads to the corresponding aziridines only when X=Y=CO2Me, and then with a very low yield.However, photolysis or evolution in the presence of trifluoroacetic acid gives good results when carried out at sufficiently low temperature.The thermolysis study of 4-6 shows a new route to 1,2,3-triazoline decomposition that has not yet been mentioned in the literature.The easy elimination of the paratoluenesulfonate or benzoate group explains this particular behaviour.

2-Aza-1,3-dienes. A New Approach to Substituted 2-Aminopyrazines

Treatment of enamines by tosylated isonitrosomalono derivatives gives access to 5-dialkylamino-1,1-dicyano 2-aza-1,3-dienes (or 1-methoxycarbonyl analogous) which are precursors of various regiospecific 5,6-substituted 2-amino-3-cyano (or methoxycarbonyl) pyrazines.Some examples of utilisation of these intermediates for synthesis of lumazines, pteridines, and other bicyclic skeletons are described.

Condensations with Oxime O-Sulfonates, I. - Synthesis of 2-Amino-4,5-dihydro-4,5-diimino-1H-pyrrole-3-carboxylates

The reaction of the oxime O-tosylates 1 with amidinoacetic acid esters 2 does not lead to the expected pyrazines 4, but rather to the novel 4,5-dihydro-1H-pyrrole-3-carboxylates 8 (= 2-pyrroline-3-carboxylates) by rearrangement via 7.The hydrolysis of the pyrroles 8 and their reactions with amines have been studied.