208935-14-2

Basic information

• Product Name: (S)-3-Benzoyl-4-methyl-5-vinyl-oxazolidin-2-one
• Synonyms: (S)-3-Benzoyl-4-methyl-5-vinyl-oxazolidin-2-one
• CAS NO: 208935-14-2
• Molecular Weight: 231.251
• Mol File: 208935-14-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-3-Benzoyl-4-methyl-5-vinyl-oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-Benzoyl-4-methyl-5-vinyl-oxazolidin-2-one(208935-14-2)
• EPA Substance Registry System: (S)-3-Benzoyl-4-methyl-5-vinyl-oxazolidin-2-one(208935-14-2)

Safety Data

• Hazardous Substances Data: 208935-14-2(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 458531-56-1 2(S)-tert-butyloxycarbonylamino-3(R,S)-hydroxypent-4-ene 

Relevant articles and documents

Palladium-catalyzed formation and stereoselective isomerization of 5- vinyloxazolines. Application to the formal synthesis of (S,S)-4-amino-3- hydroxy-5-phenylpentanoic acid

Vinyloxazolidinones have been found to undergo Pd(0)-catalyzed ionization followed by loss of carbon dioxide and subsequent cyclization to form vinyloxazolines. The reaction occurred under mild conditions, and enhancement of diastereomeric ratios with chiral substrates was obtained. 4- Benzyl-5-vinyloxazoline prepared by this method has been utilized in the stereoselective synthesis of (S,S)-4-amino-3-hydroxy-5-phenylpentanoic acid (AHPPA).