20912-70-3

Basic information

• Product Name: Benzene, 1-chloro-2-[(4-methoxyphenyl)thio]-
• CAS NO: 20912-70-3
• Molecular Formula: C13H11ClOS
• Molecular Weight: 250.749
• Mol File: 20912-70-3.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-2-[(4-methoxyphenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-2-[(4-methoxyphenyl)thio]-(20912-70-3)
• EPA Substance Registry System: Benzene, 1-chloro-2-[(4-methoxyphenyl)thio]-(20912-70-3)

Safety Data

• Hazardous Substances Data: 20912-70-3(Hazardous Substances Data)

Upstream product

• 696-63-9 4-Methoxybenzenethiol 
• 10449-07-7 (2-chlorophenyl)hydrazine 
• 3900-89-8 2-Chlorobenzeneboronic acid 
• 6320-03-2 2-chlorothiphenol 
• 104-94-9 4-methoxy-aniline 

Relevant articles and documents

Surfactant-Type Catalyst for Aerobic Oxidative Coupling of Hydrazine with Thiol in Water

A series of PEG-functionalized nitrogen ligands were developed to conduct an aerobic oxidative cross-coupling reaction between alkyl- or aryl-hydrazines with thiols in water. This surfactant-type catalyst enables high efficiencies and selectivities, while tolerating a large variety of functional groups. The mother liquor is still catalytically active after five runs.

A highly efficient heterogeneous copper-catalyzed Chan-Lam coupling between thiols and arylboronic acids leading to diaryl sulfides under mild conditions

The heterogeneous Chan-Lam coupling reaction between thiols and arylboronic acids was achieved in EtOH at room temperature in the presence of 5 mol % of MCM-41-immobilized 1,10-phenanthroline-copper(II) complex [MCM-41-1,10-Phen-CuSO4] with n-Bu4NOH (40% aq) as base under O2 atmosphere, yielding a variety of unsymmetrical diaryl sulfides in good to excellent yields under mild and green conditions. The new heterogeneous copper complex can easily be prepared by a simple procedure from commercially readily available and inexpensive reagents, and recovered by a simple filtration of the reaction solution and recycled for at least eight times without significant loss of catalytic activity.

A mild, one-pot Stadler-Ziegler synthesis of arylsulfides facilitated by photoredox catalysis in batch and continuous-flow

Visible advance: A mild, one-pot Stadler-Ziegler process for C-S bond formation has been developed. The method employs the photoredox catalyst [Ru(bpy)3Cl2]×6 H2O irradiated with visible light. A variety of aryl-alkyl and diaryl sulfides were prepared from readily available arylamines and aryl/alkylthiols in good yields. The use of a photo microreactor led to a significant improvement with respect to safety and efficiency. Copyright