209412-71-5

Basic information

• Product Name: [1-(2-Phenylamino-phenyl)-eth-(E)-ylideneaminooxy]-ethaneperoxoic acid tert-butyl ester
• Synonyms: [1-(2-Phenylamino-phenyl)-eth-(E)-ylideneaminooxy]-ethaneperoxoic acid tert-butyl ester
• CAS NO: 209412-71-5
• Molecular Weight: 356.422
• Mol File: 209412-71-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1-(2-Phenylamino-phenyl)-eth-(E)-ylideneaminooxy]-ethaneperoxoic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [1-(2-Phenylamino-phenyl)-eth-(E)-ylideneaminooxy]-ethaneperoxoic acid tert-butyl ester(209412-71-5)
• EPA Substance Registry System: [1-(2-Phenylamino-phenyl)-eth-(E)-ylideneaminooxy]-ethaneperoxoic acid tert-butyl ester(209412-71-5)

Safety Data

• Hazardous Substances Data: 209412-71-5(Hazardous Substances Data)

Upstream product

• 209412-48-6 1-(2-anilinophenyl)ethan-1-one oxime 
• 23699-74-3 1-(2-anilinophenyl)ethan-1-one 
• 75-91-2 tert.-butylhydroperoxide 
• 209412-59-9 [1-(2-Phenylamino-phenyl)-eth-(E)-ylideneaminooxy]-acetic acid 

Downstream Products

• 611-64-3 9-methyl-acridine 

Relevant articles and documents

Thermal decomposition of tert-butyl o-(phenoxy)- and o-(anilino)-phenyliminoxyperacetates

Some o-phenoxy- and o-anilino-substituted aryliminyl radicals have been generated by thermal decomposition of suitable tert-butyl iminoxyperacetates. The iminyls show no disposition to give 7-membered cyclisation on the phenyl group. In some cases, products have been found that can be rationalised through a 1,6-spirocyclisation of the iminyl radicals followed by homolytic 1,5-migration of the phenyl group from the aminic to the iminic nitrogen: this seems to be the first instance of such a process. Evidence has been found for the formation of imines through hydrogen abstraction by the iminyls; with two o-phenoxy-substituted peresters these imines have been unexpectedly isolated. The reactions have also afforded significant - in some cases major - amounts of other products (acridine, quinazolinone and indole derivatives) presumably deriving from carbon radicals: mechanisms are suggested to account for the formation of these compounds. The structure of the quinazolinone compound has been determined by X-ray crystallographic analysis.