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Upstream product

• 329914-93-4 phenylbismuth bis(2,5-dimethylbenzenesulfonate) 
• 2170-05-0 pentaphenylantimony 
• 16894-68-1 tetraphenylchloroantimony(V) 
• 264607-29-6 triphenylbismuth bis(2,5-dimethylbenzenesulfonate) 
• 609-54-1 2,5-dimethylbenzenesulfonic acid 
• 603-33-8 triphenylbismuthane 
• 603-36-1 triphenylantimony 
• 2170-05-0 pentaphenylantimony 
• 858520-12-4 μ-oxobis[(2,5-dimethylbenzenesulfonato)triphenylbismuth] 

Relevant academic research and scientific papers

Reaction of triphenylbismuth bis(arenesulfonates) with triphenylstibine

Tetraphenylantimony arenesulfonates and diphenylbismuth arenesulfonates were prepared by reaction of triphenylbismuth bis(arenesulfonates) with triphenylstibine in toluene at 25°C. The crystal and molecular structure of diphenylbismuth 2,4-dimethylbenzene

Synthesis, structure and reactions of μ- oxobis(arenesulfonatotriarylbismuth)

Hydrolysis of triarylbismuth bis(arenesulfonates) in acetone gives bismuth derivatives of the general formula [Ar3Bi(OSO2Ar')] 2O (Ar = Ph, p-Tol; Ar' = Ph, C6H4Me-4, C 6H3Me2-2,4, C6H3Me 2-3,4). The structure of μ-oxobis[(3,4-dimethylbenzenesulfonato) triphenylbismuth] was established by means of X-ray diffraction. The molecule has a linear centrosymmetric structure with the bridging oxygen atom in the inversion center. The bismuth atom has a distorted trigonal bipyramidal coordination with the bridging oxygen atom and the arenesulfonate group in axial positions. The Bi-C and Bi-Oterm distances are 2.200(2), 2.204(3), and 2.442(2) A, and the Bi-Obr distances are 2.067(1) A. 2004 MAIK "Nauka/Interperiodica".

Arylation of aryl- and diarylbismuth arenesulfonates with pentaarylantimony

Pentaarylantimony Ar3Sb (Ar = Ph, p-Tol) arylates diarylbismuth arylsulfonates Ar2BiOSO2Ar' (Ar' = C6H 4Me-4; C6H3Me2-2,4, C 6H3Me2-2,

Reactions of tetra- and triphenylantimony halides with phenylbismuth bis(arenesulfonates). Formation of a new 8-membered macroring incorporating Bi, O, and S atoms

Reactions of tetra- and triphenylantimony halides with phenylbismuth bis(2,5-dimethylbenzene)- and bis(4-methylbenzene)sulfonates in a benzene-ether solution at room temperature were used to prepare tetraphenylantimony bis[μ-(2,5-dimethylbenzenesufonato)]-bis[dichloro(phenyl)bismate(III)] (Ph4Sb+)2 · [Ph2Bi2(OSO2C6H3Me 2-2,5)2Cl4]2-, tetraphenylantimony bis[μ-(4-methylbenzenesulfonato)]-bis[chloro-(4-methylbenzenesulfonato) phenylbismate(III)] [Ph4Sb+]2[Ph2Bi2(OSO 2C6H4Me-4)4Cl2] 2- · 2C6H5, and tetraphenylantimony bis[μ-(4-methylbenzenesulfonato)]bis[bromo(4-methylbenzenesulfonato) phenylbismate(III)] [Ph4Sb+]2[Ph2Bi2(OSO 2C6H4Me-4)4Br2] 2- · 2C6H6. The structure of these ionic compounds was established by X-ray diffraction. The cation in all the compounds is (Ph4Sb)+, and in the double-charged cyclic anions the arenesulfonic group plays the role of a bridging ligand between the two bismuth-containing fragments.