16894-68-1

Basic information

• Product Name: Stibonium, tetraphenyl-, chloride
• CAS NO: 16894-68-1
• Molecular Formula: C24H20Sb.Cl
• Molecular Weight: 465.626
• Mol File: 16894-68-1.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Stibonium, tetraphenyl-, chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Stibonium, tetraphenyl-, chloride(16894-68-1)
• EPA Substance Registry System: Stibonium, tetraphenyl-, chloride(16894-68-1)

Safety Data

• Hazardous Substances Data: 16894-68-1(Hazardous Substances Data)

Upstream product

• 105242-73-7 1,1,1-triphenyl-2,1λ(5)-benzoxabismol-3(1H)-one 
• 603-36-1 triphenylantimony 
• 2170-05-0 pentaphenylantimony 
• 100-56-1 phenylmercury(II) chloride 
• 7647-01-0 hydrogenchloride 
• 13371-35-2 tetraphenylstibonium hydroxide 
• 2170-05-0 pentaphenylantimony 
• 866-55-7 dichlorodiethylstannane 
• 994-31-0 chlorotriethylstannane 
• 2279-76-7 tripropyltin chloride 
• 2373-51-5 chloro-methylsulfanyl-methane 
• 72843-81-3 acetylacetonatotriphenylantimony chloride 
• 594-31-0 triphenylantimony dichloride 
• 75136-99-1 tetraphenylantimony benzoate 

Downstream Products

• 603-36-1 triphenylantimony 
• 103-26-4 methyl cinnamate 
• 119305-89-4 (C₆H₅)4SbOOCC₆H₄COOSb(C₆H₅)4 
• 84239-06-5 (C₆H₅)4Sb⁽¹⁺⁾*BCl₄^(1-)=(C₆H₅)4SbBCl₄ 
• 84219-95-4 (C₆H₅)4Sb⁽¹⁺⁾*VCl₄^(1-)=(C₆H₅)4SbVCl₄ 
• 79110-45-5 [(C₆H₅)4Sb]⁽¹⁺⁾*[TiCl₅]^(1-)=[(C₆H₅)4Sb][TiCl₅] 
• 109423-89-4 tetraphenylantimony N,N-diethyldithiocarbamate 
• 16894-73-8 tetraphenylantimony chlorate 
• 1259321-95-3 cis-dichloro(triphenylstibine)(dimethylsulfoxide)platinum(II) 
• 103-25-3 3-phenylpropanoic acid methyl ester 
• 103-26-4 Methyl cinnamate 

Relevant articles and documents

Phenylation of Organic Derivatives of Mercury, Silicon, Tin, and Bismuth with Pentaphenylantimony and Pentaphenylphosphorus

Pentaphenylantimony and -phosphorus react with arylmercury chlorides in toluene at room temperature to give diaryl derivatives of mercury in yields of up to 95%. The reactions of pentaphenylantimony and -phosphorus with silicon and tin halides involve ary

Phenylation of Antimony(V) Organic Compounds with Pentaphenylantimony. The Structure of Tetraphenylantimony Chloride

Tetraphenylantimony chloride and bromide were synthesized through the reaction of pentaphenylantimony with diphenylantimony trichloride or tribromide taken at a molar ratio of 2:1 in toluene. When the initial compounds were taken at a molar ratio of 1:1, triphenylantimony dichloride or dibromide was formed. The phenylation of triphenylantimony sulfate with pentaphenylantimony yielded tetraphenylantimony sulfate. According to the X-ray diffraction data, the antimony atom in the tetraphenylantimony chloride molecule has a distorted trigonal bipyramidal configuration with the chlorine atom in the axial position. The Sb-Cl distance is equal to 2.686(1) and Sb-C distances are equal to 2.113(4) and 2.165(4) A (av. 2.130 A).

Arylation of organotin halides with pentaarylantimony and pentaphenylbismuth

Pentaarylantimony and pentaphenylbismuth arylate oranotin halides R3SnX and R2SnX2 (R = Alk, Ar; X = Cl, Br) in toluene at room temperature to aryltin derivatives R3SnAr and R2SnArX (initial reagent molar ratio 1:1) or R2SnAr2 (2:1) in 78-95% yield.