209746-08-7Relevant academic research and scientific papers
Rearrangement of o-(chloromethyldimethylsilyl)phenylmethoxide: Evidence for an apical position of the migrating group in a trigonal bipyramid intermediate
Hijji, Yousef M.,Hudrlik, Paul F.,Hudrlik, Anne M.
, p. 1213 - 1214 (1998)
Chloromethylsilane 5a undergoes a rearrangement reaction to give oxasilacyclopentane 9 rather than oxasilacyclohexane 10, indicating that the methyl group migrates in preference to the aryl group.
