21001-84-3Relevant academic research and scientific papers
Terminal 1-halo and 1-pseudohalo-1-alkynes via Bis(trimethylsilyl)peroxide (BTMSPO) promoted Umpolung transfer of halides and pseudohalides
Casarini,Dembech,Reginato,Ricci,Seconi
, p. 2169 - 2170 (1991)
Reaction of terminal acetylenes with readily available and inexpensive copper and zinc halides and pseudo-halides and BTMSPO has been found to be an effective and general route for obtaining, in the absence of bases and under mild conditions, 1-halo and 1-pseudohalo-1-alkynes in generally good yields.
STEPWISE CONVERSION OF OXIRANES TO ALLYLIC ALCOHOLS BY IODOTRIMETHYLSILANE AND DBU
Sakurai, Hideki,Sasaki, Koshi,Hosomi, Akira
, p. 2329 - 2332 (2007/10/02)
Iodotrimethylsilane, prepared from hexamethyldisilane and iodine, reacts smoothly with oxiranes to give (2-iodoalkoxy)trimethylsilanes which can be converted to allylic alcohols with DBU in good yields.The whole conversion can be carried out in one-pot operation.
