210413-23-3Relevant articles and documents
Insertion of imines into palladium - acyl bonds: Towards metal-catalyzed alternating copolymerization of imines with carbon monoxide to form polypeptides
Kacker, Smita,Kim, Jang Sub,Sen, Ayusman
, p. 1251 - 1253 (2007/10/03)
From a methyl ligand, CO, and an imine a chelating amide ligand is formed by insertion of the C=N bond into the metal-acyl bond in cationic palladium(II) complexes (see reaction below). The cationic acylpalladium complexes are obtained from CO and readily accessible palladium starting materials. LL = diphosphane ligand.