211110-96-2

Upstream product

• 65-85-0 benzoic acid 
• 211110-95-1 (S)-((3aR,4S,6R,6aR)-6-Methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-trifluoromethanesulfonyloxy-acetic acid ethyl ester 
• 4099-85-8 ((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methanol 
• 10257-32-6 D-ribose 
• 33985-40-9 (3aR,4S,6R,6aR)-tetrahydro-6-methoxy-2,2-dimethylfuro-[3,4-d][1,3]dioxole-4-carbaldehyde 

Downstream Products

• 205513-89-9 (S)-Benzyloxycarbonylamino-[(2R,3R,4R,5R)-3,4-diacetoxy-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-yl]-acetic acid ethyl ester 
• 205513-91-3 (S)-Benzyloxycarbonylamino-[(2R,3R,4R,5R)-3,4-diacetoxy-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-yl]-acetic acid ethyl ester 
• 151388-31-7 (S)-Benzyloxycarbonylamino-[(2R,3S,4R,5R)-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-3,4-dihydroxy-tetrahydro-furan-2-yl]-acetic acid 
• 127559-13-1 (S)-Benzyloxycarbonylamino-[(2R,3S,4R,5R)-3,4-dihydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-yl]-acetic acid 
• 24695-48-5 1-(5'-amino-5'-deoxy-α-D-allofuranuronosyl)uracil 

Relevant academic research and scientific papers

A short path synthesis of α-hydroxy ester from aldehyde using (1-ethoxyvinyl)lithium and its application to the syntheses of thymine polyoxin c and uracil polyoxin C

A short path synthesis of the α-hydroxy esters (4 and 5) from the aldehyde (3) using (1-cthoxyvinyl)lithium and its application to the total syntheses of the pyrimidine nucleoside, thymine polyoxin C (1) and uracil polyoxin C (2), are described.

(1-Ethoxyvinyl)lithium in the total synthesis of thymine polyoxin C and uracil polyoxin C

A short path synthesis of the ethyl (methyl 2,3-O-isopropylidene-β-D- allofuranosid)uronate (5) and ethyl (methyl 2,3-O-isopropylidene-α-L- talofuranosid)uronate (6) from methyl 2,3-O-isopropylidene-β-D- ribopentodialdo-1,4-furanoside (3) using (1-ethoxyvinyl)lithium and its application to the total synthesis of the pyrimidine nucleosides, thymine polyoxin C (1) and uracil polyoxin C (2), are described.