211183-10-7Relevant academic research and scientific papers
Electron transfer in a hydrogen-bonded assembly consisting of porphyrin-diimide
Osuka, Atsuhiro,Yoneshima, Ryusho,Shiratori, Hideo,Okada, Tadashi,Taniguchi, Seiji,Mataga, Noboru
, p. 1567 - 1568 (1998)
Electron-transfer reactions in an H-bonded assembly composed of a diacylaminopyridine bearing zinc porphyrin and 1,8:4,5-naphthalenetetracarboxylic diimide(Ka = 2.8 × 102 dm3 mol-1) in benzene occur with kCS = 4.1 × 1010 s-1 and kCR = 3.7 × 109 s-1, while the corresponding covalently linked model with a comparable distance and energy gap undergoes electron transfer with kCS = 9.9 × 1010 s-1 and kCR = 6.7 × 108 s-1.
