2113-47-5

Basic information

• Product Name: ACETAMIDOBIPHENYL
• Synonyms: ACETAMIDOBIPHENYL
• CAS NO: 2113-47-5
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.28
• Mol File: 2113-47-5.mol
• Article Data: 3

Chemical Properties

• Melting Point: 121°C
• Boiling Point: 350.95°C (rough estimate)
• Flash Point: 225.5°C
• Appearance: /
• Density: 1.0694 (rough estimate)
• Vapor Pressure: 3.22E-05mmHg at 25°C
• Refractive Index: 1.5780 (estimate)
• CAS DataBase Reference: ACETAMIDOBIPHENYL(CAS DataBase Reference)
• NIST Chemistry Reference: ACETAMIDOBIPHENYL(2113-47-5)
• EPA Substance Registry System: ACETAMIDOBIPHENYL(2113-47-5)

Safety Data

• Hazardous Substances Data: 2113-47-5(Hazardous Substances Data)

Usage

Uses

2''-Phenylacetanilide is an intermediate in the synthesis of 2,2'',3,3'',4,4'',5,5'',6-Nonabromobiphenyl (N649580) which is a polybrominated biphenyl compound that poses toxic dangers to animals, humans and the environment. 2,2'',3,3'',4,4'',5,5'',6-Nonabromobipheny is also one of the components of Firemaster FF-1, a polybrominated biphenyl fire retardant.

InChI:InChI=1/C14H13NO/c1-11(16)15-14-10-6-5-9-13(14)12-7-3-2-4-8-12/h2-10H,1H3,(H,15,16)

Upstream product

• 533-17-5 N-(2-chlorophenyl)acetamide 
• 98-80-6 phenylboronic acid 
• 90-41-5 2-phenylaniline 
• 4232-27-3 2,4-dinitrophenyl acetate 
• 201230-82-2 carbon monoxide 
• 318-13-8 [1,1'-biphenyl]-2-diazonium tetrafluoroborate 
• 64-17-5 ethanol 
• 106736-41-8 N-biphenyl-2-yl-N-bromo-acetamide 
• 64-19-7 acetic acid 
• 860572-11-8 N-biphenyl-2-yl-N-chloro-acetamide 

Downstream Products

• 7148-08-5 N-(5-chloro-[1,1'-biphenyl]-2-yl)acetamide 
• 1451075-18-5 N-acetyl-2-methyl-7-phenyl-1H-indole 

Relevant articles and documents

An N-Heterocyclic Carbene-Nickel Half-Sandwich Complex as a Precatalyst for Suzuki-Miyaura Coupling of Aryl/Heteroaryl Halides with Aryl/Heteroarylboronic Acids

A nickel half-sandwich complex supported by our original NHC ligand was developed as a robust precatalyst for Suzuki-Miyaura cross-coupling. The addition of PPh3 was a crucial element in the suppression of side reactions and in accelerating the cross-coupling reaction. By employing the optimal conditions, aryl-aryl, heteroaryl-aryl, and heteroaryl-heteroaryl couplings were achieved.

REACTION OF DIAZONIUM SALTS WITH TRANSITION METALS X. FORMYLATION OF ARENEDIAZONIUM SALTS WITH CARBON MONOXIDE AND SILYL HYDRIDES UNDER PALLADIUM CATALYSIS

Arenediazonium tetrafluoroborates (ArN2BF4 where Ar = X-C6H4; X = H, 2-Me, 3-Me, 4-Me, 4-MeO, 4-MeCO, 4-EtOCO, 2-Ph, 2-Cl, 3-Cl, 4-Cl, 4-Br, 4-I, 3-NO2 and 4-NO2) were easily converted to aromatic aldehydes (ArCHO) in good yields through the palladium-catalyzed reaction with CO and Et3SiH or polymethylhydrosiloxane (PHMS) at room temperature.