2114-11-6

Basic information

• Product Name: allyl carbamate
• Synonyms: Carbamic acid 2-propenyl;Carbamic acid 2-propenyl ester;Carbamic acid allyl;Carbamic acid allyl ester;Allyl carbamate 95%
• CAS NO: 2114-11-6
• Molecular Formula: C₄H₇NO₂
• Molecular Weight: 101.12
• EINECS: 218-309-6
• Mol File: 2114-11-6.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 189.47°C (rough estimate)
• Flash Point: 100℃
• Appearance: /
• Density: 1.077 g/mL at 25 °C
• Vapor Pressure: 0.218mmHg at 25°C
• Refractive Index: n20/D1.454
• Storage Temp.: ?20°C
• CAS DataBase Reference: allyl carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: allyl carbamate(2114-11-6)
• EPA Substance Registry System: allyl carbamate(2114-11-6)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-41-50
• Safety Statements: 26-39-61
• RIDADR: UN 3077 9 / PGIII
• WGK Germany: 2
• Hazardous Substances Data: 2114-11-6(Hazardous Substances Data)

Usage

General Description

Allyl carbamate, also known as allyl urethane, is a chemical compound with the molecular formula C4H7NO2. It is an organic compound that is derived from allyl alcohol and carbamic acid. Allyl carbamate is used in the production of polymers, resins, and pesticides. It is also used as a building block in the synthesis of pharmaceuticals and as a monomer in the production of various polymeric materials. Allyl carbamate is a colorless, flammable liquid with a strong odor, and it is classified as a hazardous substance that can cause skin and eye irritation, and is toxic if ingested or inhaled. It is important to handle and use allyl carbamate with caution and to follow proper safety protocols to minimize the risk of exposure.

InChI:InChI=1/C4H7NO2/c1-2-3-7-4(5)6/h2H,1,3H2,(H2,5,6)

Upstream product

• 107-18-6 allyl alcohol 
• 57-13-6 urea 
• 70670-66-5 (2,2,2-trichloroacetyl)carbamic acid allyl ester 
• 590-28-3 potassium cyanate 
• 1476-23-9 allylisocyanate 
• 9004-64-2 hydroxypropylcellulose 
• 917-61-3 sodium isocyanate 
• 2937-50-0 Allyl chloroformate 
• 75-44-5 phosgene 

Downstream Products

• 107-18-6 allyl alcohol 
• 921767-14-8 C₁₇H₁₆BrNO₄S 
• 1004307-38-3 C₁₈H₁₇NO₆S 
• 921767-33-1 C₁₅H₁₅NO₄S₂ 
• 921767-16-0 C₁₅H₁₅NO₅S 
• 18992-89-7 allyl N-phenylcarbamate 
• 23794-82-3 allyl (4-(trifluoromethyl)phenyl)carbamate 
• 1375476-08-6 C₁₉H₂₀N₂O₄ 
• 921767-12-6 (benzenesulfonyl-phenyl-methyl)-carbamic acid allyl ester 
• 1220349-89-2 allyl (1-(phenylsulfonyl)pent-4-en-1-yl)carbamate 
• 1098197-65-9 (5R,6S,E)-methyl 6-(allyloxycarbonylamino)-6-(3-methoxyphenyl)-5-methylhex-3-enoate 

Relevant articles and documents

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An Fe3O4@SiO2/Schiff base/Cu(ii) complex as an efficient recyclable magnetic nanocatalyst for selective mono: N-arylation of primary O-alkyl thiocarbamates and primary O-alkyl carbamates with aryl halides and arylboronic acids

An efficient, convenient and novel method for the selective mono N-arylation of primary O-alkyl thiocarbamates and primary O-alkyl carbamates with aryl halides and arylboronic acids in the presence of a recyclable magnetic Cu(ii) nanocatalyst is described. A variety of mono N-arylated O-alkyl thiocarbamates and O-alkyl carbamates were prepared in good to excellent yields with a broad range of aryl coupling partners. The magnetic nanocatalyst can be easily recovered with an external magnetic field and reused at least five times without noticeable leaching or loss of its catalytic activity. This cost-effective and eco-friendly methodology has some other advantages, such as easy preparation of the catalyst, simple workup procedure, and easy purification, which makes this protocol interesting for the users in various fields of pharmacology and biotechnology systems.

4-Dodecylbenzenesulfonic acid (DBSA) promoted solvent-free diversity-oriented synthesis of primary carbamates, S-thiocarbamates and ureas

A simple and highly efficient solvent-free method for the conversion of alcohols, phenols, thiols and amines to primary carbamates, S-thiocarbamates and ureas in the presence of 4-dodecylbenzenesulfonic acid (DBSA) as a cheap and green Bronsted acid reagent has been described. All products were obtained in good to excellent yields and characterized using FT-IR, 1H- and 13C-NMR, MS and CHNS techniques.