211616-59-0

Basic information

• Product Name: Acetic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-3-fluoro-tetrahydro-thiophen-2-yl ester
• CAS NO: 211616-59-0
• Molecular Weight: 390.476
• Mol File: 211616-59-0.mol

Chemical Properties

• CAS DataBase Reference: Acetic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-3-fluoro-tetrahydro-thiophen-2-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-3-fluoro-tetrahydro-thiophen-2-yl ester(211616-59-0)
• EPA Substance Registry System: Acetic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-3-fluoro-tetrahydro-thiophen-2-yl ester(211616-59-0)

Safety Data

• Hazardous Substances Data: 211616-59-0(Hazardous Substances Data)

Upstream product

• 218601-09-3 Benzoic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-tetrahydro-thiophen-3-yl ester 
• 108-24-7 acetic anhydride 
• 211616-58-9 (2S,3R,4R)-3-Benzyloxy-2-benzyloxymethyl-4-fluoro-tetrahydro-thiophene 

Downstream Products

• 211616-60-3 1-((3R,4R,5S)-4-Benzyloxy-5-benzyloxymethyl-3-fluoro-tetrahydro-thiophen-2-yl)-5-methyl-1H-pyrimidine-2,4-dione 

Relevant articles and documents

Synthesis and antiviral activity of L-2'-deoxy-2'-up-fluoro-4'- thionucleosides

L-2'-Deoxy-2'-up-fluoro-4'-thionucleosides were efficiently synthesized from D-xylose via L-4-thioarabitol derivative as a key intermediate and evaluated for antiviral activities against HIV-1, HSV-1,2 and HBV.

Ring contraction and rearrangement of 4-thiofuranose derivatives observed during dast fluorination in the synthesis of L-2'-'up'-fluoro-4'- thiothymidine

Ring contraction and rearrangement of 4-thiofuranose derivatives were observed through the regioselective opening of the episulfonium ion formed during DAST fluorination in the synthesis of L-2'-'up'-fluoro-4'- thiothymidine.