218601-09-3

Basic information

• Product Name: Benzoic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-tetrahydro-thiophen-3-yl ester
• Synonyms: Benzoic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-tetrahydro-thiophen-3-yl ester
• CAS NO: 218601-09-3
• Molecular Weight: 434.556
• Mol File: 218601-09-3.mol

Chemical Properties

• CAS DataBase Reference: Benzoic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-tetrahydro-thiophen-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-tetrahydro-thiophen-3-yl ester(218601-09-3)
• EPA Substance Registry System: Benzoic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-tetrahydro-thiophen-3-yl ester(218601-09-3)

Safety Data

• Hazardous Substances Data: 218601-09-3(Hazardous Substances Data)

Upstream product

• 65-85-0 benzoic acid 
• 210548-19-9 (3R,4R,5S)-4-Benzyloxy-5-benzyloxymethyl-tetrahydro-thiophen-3-ol 

Downstream Products

• 211616-60-3 1-((3R,4R,5S)-4-Benzyloxy-5-benzyloxymethyl-3-fluoro-tetrahydro-thiophen-2-yl)-5-methyl-1H-pyrimidine-2,4-dione 
• 211616-59-0 Acetic acid (3R,4R,5S)-4-benzyloxy-5-benzyloxymethyl-3-fluoro-tetrahydro-thiophen-2-yl ester 
• 211616-58-9 (2S,3R,4R)-3-Benzyloxy-2-benzyloxymethyl-4-fluoro-tetrahydro-thiophene 
• 210548-23-5 N-[1-((2R,4R,5S)-4-Benzyloxy-5-benzyloxymethyl-3,3-difluoro-tetrahydro-thiophen-2-yl)-2-oxo-1,2-dihydro-pyrimidin-4-yl]-benzamide 
• 210548-24-6 N-[1-((2S,4R,5S)-4-Benzyloxy-5-benzyloxymethyl-3,3-difluoro-tetrahydro-thiophen-2-yl)-2-oxo-1,2-dihydro-pyrimidin-4-yl]-benzamide 
• 210548-37-1 N-[1-((2R,4R,5S)-3,3-Difluoro-4-hydroxy-5-hydroxymethyl-tetrahydro-thiophen-2-yl)-2-oxo-1,2-dihydro-pyrimidin-4-yl]-benzamide 
• 210548-33-7 (4R,5S)-4-Benzyloxy-5-benzyloxymethyl-dihydro-thiophen-3-one 
• 210548-20-2 (2S,3R)-3-Benzyloxy-2-benzyloxymethyl-4,4-difluoro-tetrahydro-thiophene 
• 210548-21-3 (2S,3R)-3-Benzyloxy-2-benzyloxymethyl-4-methylene-tetrahydro-thiophene 
• 218601-19-5 Benzoic acid (3R,4R,5S)-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-fluoro-tetrahydro-thiophen-3-yl ester 
• 218601-25-3 Benzoic acid (3S,4R,5S)-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-fluoro-tetrahydro-thiophen-3-yl ester 
• 218601-22-0 (3R,4R,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-fluoro-tetrahydro-thiophen-3-ol 
• 218601-27-5 (3S,4R,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-fluoro-tetrahydro-thiophen-3-ol 
• 218601-29-7 3-Benzoyl-1-[(3R,4R,5S)-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-fluoro-tetrahydro-thiophen-3-yl]-1H-pyrimidine-2,4-dione 

Relevant articles and documents

Participation of sulfur occurred during the Mitsunobu reaction: Synthesis of novel isodideoxythionucleosides

Novel isodideoxythionucleosides have been synthesized from our versatile intermediate, L-4-thioarabitol derivative 5 using the Mitsunobu reaction as a key step. It is found that the sulfur atom of the 4-thiofuranose derivative takes part in the Mitsunobu

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Ring contraction and rearrangement of 4-thiofuranose derivatives observed during dast fluorination in the synthesis of L-2'-'up'-fluoro-4'- thiothymidine

Ring contraction and rearrangement of 4-thiofuranose derivatives were observed through the regioselective opening of the episulfonium ion formed during DAST fluorination in the synthesis of L-2'-'up'-fluoro-4'- thiothymidine.