212184-58-2

Basic information

• Product Name: 2,4-Octadienoic acid, 8-(phenylmethoxy)-, ethyl ester, (2E,4E)-
• CAS NO: 212184-58-2
• Molecular Formula: C17H22O3
• Molecular Weight: 274.36
• Mol File: 212184-58-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,4-Octadienoic acid, 8-(phenylmethoxy)-, ethyl ester, (2E,4E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Octadienoic acid, 8-(phenylmethoxy)-, ethyl ester, (2E,4E)-(212184-58-2)
• EPA Substance Registry System: 2,4-Octadienoic acid, 8-(phenylmethoxy)-, ethyl ester, (2E,4E)-(212184-58-2)

Safety Data

• Hazardous Substances Data: 212184-58-2(Hazardous Substances Data)

Upstream product

• 693-02-7 hex-1-yne 
• 1002-36-4 hep-2-yn-1-ol 
• 63478-76-2 1-hydroxy-6-heptyne 
• 565473-04-3 ((hept-6-yn-1-yloxy)methyl)benzene 
• 921207-66-1 ethyl 8-benzyloxy-oct-2-ynoate 

Downstream Products

• 921207-77-4 ethyl (4S,5S,E)-8-(benzyloxy)-4,5-dihydroxyoct-2-enoate 
• 570397-58-9 (3S,5R,7R)-7-(benzyloxy)-3-[3-(benzyloxy)propyl]-5-hydroxy-14-methoxy-3,4,5,6,7,8-hexahydro-1H-2-benzoxacyclododecin-1-one 
• 921207-73-0 methyl 2-{(1E,4R)-4-benzyloxy-5-[(2S,4R,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-enyl}-6-methoxy-benzoate 
• 921207-64-9 (4R)-4-benzyloxy-5-[(2S,4R,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-ene 
• 921207-71-8 (4R)-5-[(2S,4S,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-en-4-ol 
• 921207-70-7 5-{(2S,4S,6S)-6-[3-(benzyloxy)propyl]-2-phenyl-1,3-dioxan-4-yl}-1-penten-4-one 
• 921207-65-0 ethyl 2-{(2S,4S,6S)-6-[3-(benzyloxy)propyl]-2-phenyl-1,3-dioxan-4-yl}acetate 
• 921207-68-3 ethyl (E)-(5S)-8-(benzyloxy)-5-hydroxy-2-octenoate 

Relevant articles and documents

Towards the synthesis of Palmerolide A: asymmetric synthesis of C1-C14 fragment

The synthesis of a C1-C14 fragment of a marine cytotoxic natural product Palmerolide A is described. The key steps involved in this synthesis are deoxygenative rearrangement of an alkynol followed by an asymmetric dihydroxylation of a diene ester and CBS-

Claisen rearrangement of γ-hydroxyvinyl sulfones via ketene acetal derivatives. A new entry to functionalized (2E,4E)-alkadienoic esters

In situ prepared ketene acetals of γ-hydroxyvinyl sulfones undergo a Claisen rearrangement affording 3-phenylsulfonyl esters. These compounds are convened to (2E,4E)-dienoic esters by a base-assisted elimination of benzenesulfinic acid.