921207-71-8

Basic information

• Product Name: (4R)-5-[(2S,4S,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-en-4-ol
• Synonyms: (4R)-5-[(2S,4S,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-en-4-ol
• CAS NO: 921207-71-8
• Molecular Weight: 396.527
• Mol File: 921207-71-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4R)-5-[(2S,4S,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-en-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (4R)-5-[(2S,4S,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-en-4-ol(921207-71-8)
• EPA Substance Registry System: (4R)-5-[(2S,4S,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-en-4-ol(921207-71-8)

Safety Data

• Hazardous Substances Data: 921207-71-8(Hazardous Substances Data)

Upstream product

• 212184-58-2 ethyl (2E,4E)-8-(benzyloxy)octa-2,4-dienoate 
• 693-02-7 hex-1-yne 
• 1002-36-4 hep-2-yn-1-ol 
• 63478-76-2 1-hydroxy-6-heptyne 
• 921207-65-0 ethyl 2-{(2S,4S,6S)-6-[3-(benzyloxy)propyl]-2-phenyl-1,3-dioxan-4-yl}acetate 
• 921207-67-2 ethyl (4S,5S)-3-[(3-benzyloxy-propyl)-2-oxo-[1,3]dioxolan-4-yl] acrylate 
• 921207-66-1 ethyl 8-benzyloxy-oct-2-ynoate 
• 565473-04-3 ((hept-6-yn-1-yloxy)methyl)benzene 
• 943768-65-8 2-(2S,4R,6S)-6-[3-(benzyloxy)propyl]-2-phenyl-1,3-dioxan-4-yl-1-ethanol 
• 915141-48-9 2-[(2S,4S,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]acetaldehyde 
• 547713-49-5 (3aS,7aS)-1,3-bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-(2-propenyl)-1H-1,3,2-benzodiazasilole 
• 921207-70-7 5-{(2S,4S,6S)-6-[3-(benzyloxy)propyl]-2-phenyl-1,3-dioxan-4-yl}-1-penten-4-one 

Downstream Products

• 921207-73-0 methyl 2-{(1E,4R)-4-benzyloxy-5-[(2S,4R,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-enyl}-6-methoxy-benzoate 
• 570397-58-9 (3S,5R,7R)-7-(benzyloxy)-3-[3-(benzyloxy)propyl]-5-hydroxy-14-methoxy-3,4,5,6,7,8-hexahydro-1H-2-benzoxacyclododecin-1-one 
• 921207-64-9 (4R)-4-benzyloxy-5-[(2S,4R,6S)-6-(3-benzyloxy-propyl)-2-phenyl-1,3-dioxan-4-yl]pent-1-ene 

Relevant articles and documents

De novo formal synthesis of (-)-apicularen A via an iterative asymmetric hydration sequence

(Chemical Equation Presented) A de novo approach to the formal total synthesis of the macrolide natural product (-)-apicularen A has been achieved in 18 steps'from achiral starting materials. Both the absolute and relative stereochemistries of apicularen A were introduced by a Sharpless asymmetric dihydroxylation, a π-allyl-palladium catalyzed reduction, a stereoselective reduction, and a base-promoted transannulation to install the C-9 stereocenter.