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Rh(OPh)(PPh3)3 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

21276-23-3

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21276-23-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 21276-23-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,1,2,7 and 6 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 21276-23:
(7*2)+(6*1)+(5*2)+(4*7)+(3*6)+(2*2)+(1*3)=83
83 % 10 = 3
So 21276-23-3 is a valid CAS Registry Number.

21276-23-3Relevant academic research and scientific papers

Preparation, structure and properties of triphenylphosphine rhodium aryloxides

Kuznetsov, Vladimir F.,Yap, Glenn P.A.,Bensimon, Corinne,Alper, Howard

, p. 172 - 182 (2008/10/08)

The reaction of Wilkinson's catalyst with NaOAr in toluene cleanly affords the corresponding aryloxide complexes Rh(PPh3)3OAr (1). In solution, 1 exists in equilibrium with PPh3 and the corresponding Rh(PPh3)su

REGIOSELECTIVE C-O BOND CLEAVAGE OF ALLYLIC PHENYL CARBONATES PROMOTED BY GROUP 8 TRANSITION METAL HYDRIDO COMPLEXES

Hayashi, Yoshinori,Komiya, Sanshiro,Yamamoto, Takakazu,Yamamoto, Akio

, p. 977 - 980 (2007/10/02)

Carbon-oxygen bonds in allylic phenyl carbonates are selectively cleaved by hydrido complexes of Co, Ru and Rh to give Co(OPh)L3, Ru(OPh)L2 and Rh(OPh)L3 with liberation of propylene and CO2.An intermediate complex RuH(O2COEt)L3 has been isolated in the reaction of RuH2(PPh3)4 with allyl ethyl carbonate.Reaction mechanisms are also discussed.

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