16308-68-2

Basic information

• Product Name: ALLYL PHENYL CARBONATE 97
• Synonyms: ALLYL PHENYL CARBONATE 97;Carbonic Acid Allyl Phenyl Ester;Carbonic acid, phenyl2-propen-1-yl ester
• CAS NO: 16308-68-2
• Molecular Formula: C₁₀H₁₀O₃
• Molecular Weight: 178.186
• Product Categories: Carbonates;Carbonyl Compounds;Organic Building Blocks
• Mol File: 16308-68-2.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 67-70 °C0.3 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.096 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0195mmHg at 25°C
• Refractive Index: n20/D 1.4990(lit.)
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: ALLYL PHENYL CARBONATE 97(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL PHENYL CARBONATE 97(16308-68-2)
• EPA Substance Registry System: ALLYL PHENYL CARBONATE 97(16308-68-2)

Safety Data

• Hazard Codes: Xn
• Statements: 22-36-43
• Safety Statements: 26-36/37/39
• WGK Germany: 3
• Hazardous Substances Data: 16308-68-2(Hazardous Substances Data)

Usage

Uses

Allyl phenyl carbonate can react with (2-alkynyl)phenylisocyanate, catalyzed P(0)/Cu(I) system to give the corresponding indole.

General Description

Allyl phenyl carbonate can be obtained via by reacting phenyl chloroformate and allyl alcohol in presence of pyridine.

InChI:InChI=1/C10H10O3/c1-2-8-12-10(11)13-9-6-4-3-5-7-9/h2-7H,1,8H2

Upstream product

• 32315-10-9 bis(trichloromethyl) carbonate 
• 107-18-6 allyl alcohol 
• 108-95-2 phenol 
• 2937-50-0 Allyl chloroformate 
• 1885-14-9 phenyl chloroformate 
• 102-09-0 bis(phenyl) carbonate 

Downstream Products

• 41423-02-3 Carbonic acid 3-(methoxy-dimethyl-silanyl)-propyl ester phenyl ester 
• 187737-37-7 propene 
• 1746-13-0 allyl phenyl ether 
• 184292-16-8 (6-aminohexyl)carbamic acid allyl ester 
• 223741-66-0 1-N-(allyloxycarbonyl)-1,2-diaminoethane 
• 117499-16-8 bis(2-tert-butyloxycarbonylaminoethyl)amine 
• 503817-49-0 (2-amino-2-methylpropyl)carbamic acid allyl ester 
• 91583-66-3 phenoxotris(triphenylphosphine)cobalt(I) 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

A mild ligand-free iron-catalyzed liberation of alcohols from allylcarbonates

Different from most carbonates the allyloxy carbonyl protecting group can be cleaved under neutral conditions using metal catalysis. However, most of the catalysts employed to date are based upon precious metals. Herein we present two protocols for the mild Fe-catalyzed liberation of alcohols from allylcarbonates that are characterized by broad functional group tolerance and exclusive chemoselectivity.

Expanding the scope and orthogonality of PNA synthesis

Peptide nucleic acids (PNAs) hybridize to natural oligonucleotides according to Watson and Crick base-pairing rules. The robustness of PNA oligomers and ease of synthesis have made them an attractive platform to encode small or macromolecules for microarr

A bimetallic catalyst and dual role catalyst: Synthesis of N-(alkoxycarbonyl)indoles from 2-(alkynyl)phenylisocyanates

3-Allyl-N-(alkoxycarbonyl)indoles are synthesized via the reaction of 2-(alkynyl)phenylisocyanates and allyl carbonates in the presence of Pd(PPh3)4 (1 mol %) and CuCl (4 mol %) bimetallic catalyst. It is most probable that Pd0