213385-33-2

Basic information

• Product Name: 3-Pentanone, 1-[(4-methoxyphenyl)methoxy]-2-methyl-, (2R)-
• CAS NO: 213385-33-2
• Molecular Formula: C14H20O3
• Molecular Weight: 236.311
• Mol File: 213385-33-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3-Pentanone, 1-[(4-methoxyphenyl)methoxy]-2-methyl-, (2R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentanone, 1-[(4-methoxyphenyl)methoxy]-2-methyl-, (2R)-(213385-33-2)
• EPA Substance Registry System: 3-Pentanone, 1-[(4-methoxyphenyl)methoxy]-2-methyl-, (2R)-(213385-33-2)

Safety Data

• Hazardous Substances Data: 213385-33-2(Hazardous Substances Data)

Upstream product

• 212051-35-9 (R)-methyl 3-((4-methoxybenzyl)oxy)-2-methylpropanoate 
• 680201-71-2 1-hydroxy-2-(hydroxymethyl)-3-pentanone 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 680201-78-9 Methanesulfonic acid (S)-2-(4-methoxy-benzyloxymethyl)-3-oxo-pentyl ester 
• 680201-70-1 1-benzyloxy-2-(benzyloxymethyl)-3-pentanone 
• 680201-69-8 1-benzyloxy-2-(benzyloxymethyl)-3-pentanol 
• 680201-81-4 (R)-2-hydroxymethyl-1-(4-methoxybenzyloxy)-3-pentanone 
• 680201-75-6 2-hydroxymethyl-1-(4-methoxybenzyloxy)-3-pentanone 
• 449173-99-3 (2R,3RS)-1-(4-methoxybenzyloxy)-2-methyl-pentan-3-ol 
• 925-90-6 ethylmagnesium bromide 
• 27970-79-2 (R)-2-Methyl-3-oxopentanol 
• 449174-20-3 methyl (R)-N-methyl-N-methoxy-3-(4-methoxybenzyloxy)-2-methylpropanoate 

Downstream Products

• 213385-34-3 (7R,8R,10R)-7-Hydroxy-11-(4-methoxy-benzyloxy)-8,10-dimethyl-9-oxo-undec-2-ynoic acid methyl ester 
• 1440972-37-1 C₁₆H₂₄O₄ 
• 1453868-14-8 (2R,4R)-1-hydroxy-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentan-3-one 
• 1453868-15-9 (2S,4R)-1-hydroxy-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentan-3-one 

Relevant articles and documents

Stereocontrolled synthesis of 1,3-diols from enones: Cooperative lewis base-mediated intramolecular carbonyl hydrosilylations

A streamlined synthesis of β-hydroxy ketone substrates has been developed to further investigate a recently discovered cooperative Lewis base-mediated intramolecular carbonyl hydrosilylation reaction. The synthesis features an enone β-borylation/oxidation

Studies towards the synthesis of the C(9)-C(20) lactone-dipropionate fragment of calyculin C

In this paper we describe the synthesis of a diastereomer of the C(9)-C(20) dipropionate-lactone fragment of Calyculin C. A short and enantioselective synthesis of the key intermediate 2 has been developed. This intermediate will play a critical role also

Toward the combinatorial synthesis of polyketide libraries: Asymmetric aldol reactions with α-chiral aldehydes on solid support

(Matrix presented) The viability of performing stereocontrolled aldol additions with α-chiral aldehydes attached by a silyl linker to a hydroxymethylpolystyrene resin is demonstrated for boron and titanium enolates. Subsequent ketone reduction and manipul