213385-33-2

Upstream product

• 449173-99-3 (2R,3RS)-1-(4-methoxybenzyloxy)-2-methyl-pentan-3-ol 
• 212051-35-9 (R)-methyl 3-((4-methoxybenzyl)oxy)-2-methylpropanoate 
• 680201-71-2 1-hydroxy-2-(hydroxymethyl)-3-pentanone 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 680201-75-6 2-hydroxymethyl-1-(4-methoxybenzyloxy)-3-pentanone 
• 925-90-6 ethylmagnesium bromide 
• 27970-79-2 (R)-2-Methyl-3-oxopentanol 
• 680201-78-9 Methanesulfonic acid (S)-2-(4-methoxy-benzyloxymethyl)-3-oxo-pentyl ester 
• 680201-70-1 1-benzyloxy-2-(benzyloxymethyl)-3-pentanone 
• 680201-69-8 1-benzyloxy-2-(benzyloxymethyl)-3-pentanol 
• 680201-81-4 (R)-2-hydroxymethyl-1-(4-methoxybenzyloxy)-3-pentanone 
• 449174-20-3 methyl (R)-N-methyl-N-methoxy-3-(4-methoxybenzyloxy)-2-methylpropanoate 

Downstream Products

• 1453868-16-0 (2R,3S,4R)-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentane-1,3-diol 
• 1453868-17-1 (2S,3R,4R)-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentane-1,3-diol 
• 1453868-18-2 (4S,5S)-4-((R)-1-((4-methoxybenzyl)oxy)propan-2-yl)-5-methyl-1,3-dioxan-2-one 
• 1453868-20-6 (S)-4-benzyl-3-((2S,3R,4S,5R,6R)-3,5-dihydroxy-7-((4-methoxybenzyl)oxy)-2,4,6-trimethylheptanoyl)oxazolidin-2-one 
• 1453868-19-3 (2S,3R,4R)-3-hydroxy-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentanal 
• 1453868-14-8 (2R,4R)-1-hydroxy-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentan-3-one 
• 1453868-15-9 (2S,4R)-1-hydroxy-5-((4-methoxybenzyl)oxy)-2,4-dimethylpentan-3-one 

Relevant academic research and scientific papers

Stereocontrolled synthesis of 1,3-diols from enones: Cooperative lewis base-mediated intramolecular carbonyl hydrosilylations

A streamlined synthesis of β-hydroxy ketone substrates has been developed to further investigate a recently discovered cooperative Lewis base-mediated intramolecular carbonyl hydrosilylation reaction. The synthesis features an enone β-borylation/oxidation

Enantioselective preparation of asymmetrically protected 2-propanoyl-1,3-propanediol derivatives: Toward the total synthesis of Kazusamycin A

The preparation of enantiomerically pure 2-propanoyl-1,3-propanediol derivatives, key intermediates in our studies on total synthesis of the potent antitumor compound Kazusamycin A are described. After various enzymatic protocols for desymmetrization of t

Studies towards the synthesis of the C(9)-C(20) lactone-dipropionate fragment of calyculin C

In this paper we describe the synthesis of a diastereomer of the C(9)-C(20) dipropionate-lactone fragment of Calyculin C. A short and enantioselective synthesis of the key intermediate 2 has been developed. This intermediate will play a critical role also

Total synthesis and structural elucidation of (-)-delactonmycin

The key steps in the total synthesis of delactonmycin (1) involved a Wittig olefination, a Negishi coupling, and an aldol reaction. The polyketide, which was isolated from Streptomyces sp., displays potent inhibitory activity of the nucleocytoplasmic tran

Toward the combinatorial synthesis of polyketide libraries: Asymmetric aldol reactions with α-chiral aldehydes on solid support

(Matrix presented) The viability of performing stereocontrolled aldol additions with α-chiral aldehydes attached by a silyl linker to a hydroxymethylpolystyrene resin is demonstrated for boron and titanium enolates. Subsequent ketone reduction and manipul