680201-75-6

Upstream product

• 680201-70-1 1-benzyloxy-2-(benzyloxymethyl)-3-pentanone 
• 680201-69-8 1-benzyloxy-2-(benzyloxymethyl)-3-pentanol 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 680201-71-2 1-hydroxy-2-(hydroxymethyl)-3-pentanone 

Downstream Products

• 449173-99-3 (2R,3RS)-1-(4-methoxybenzyloxy)-2-methyl-pentan-3-ol 
• 213385-33-2 (R)-1-((4-methoxybenzyl)oxy)-2-methylpentan-3-one 
• 680201-78-9 Methanesulfonic acid (S)-2-(4-methoxy-benzyloxymethyl)-3-oxo-pentyl ester 
• 753016-45-4 (E)-(2S,3S,4S,5R,6S)-10-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxymethyl)-4,6,8-trimethyl-dec-8-ene-3,5-diol 
• 753016-44-3 (E)-(2S,4S,5R,6S)-10-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-5-hydroxy-2-(4-methoxy-benzyloxymethyl)-4,6,8-trimethyl-dec-8-en-3-one 
• 753016-68-1 (4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-5-((E)-2-methyl-3-triisopropylsilanyloxy-propenyl)-[1,3]dioxane 
• 860160-10-7 (E)-3-{(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-2-methyl-acrylic acid ethyl ester 
• 753016-46-5 ((E)-(1R,2S)-6-Benzyloxy-1-{(R)-1-[(4S,5S)-5-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-ethyl}-2,4-dimethyl-hex-4-enyloxy)-tert-butyl-dimethyl-silane 
• 753016-67-0 (E)-3-{(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-2-methyl-prop-2-en-1-ol 
• 753016-66-9 {(4S,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxan-5-yl}-methanol 
• 753016-65-8 (E)-(2S,3R,4S)-8-Benzyloxy-2-[(4S,5S)-5-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-[1,3]dioxan-4-yl]-4,6-dimethyl-oct-6-en-3-ol 
• 753016-64-7 (E)-(2R,3S,4S,5R,6S)-10-Benzyloxy-2-(4-methoxy-benzyloxymethyl)-4,6,8-trimethyl-dec-8-ene-1,3,5-triol 
• 753016-47-6 (4R,5S)-4-[(E)-(1R,2R,3S)-7-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-hept-5-enyl]-2,2-dimethyl-[1,3]dioxane-5-carbaldehyde 
• 680201-67-6 (S)-1-(tert-butyldiphenylsiloxy)-2-(4-methoxybenzyloxymethyl)-3-pentanone 

Relevant academic research and scientific papers

A practical synthesis of (-)-kazusamycin A (revised)

We describe herein a stereo-controlled and practical synthesis of three key building blocks, namely Segment AB′, Segment D, and Segment E′ needed for the total synthesis of (-)-kazusamycin A.

Enantioselective preparation of asymmetrically protected 2-propanoyl-1,3-propanediol derivatives: Toward the total synthesis of Kazusamycin A

The preparation of enantiomerically pure 2-propanoyl-1,3-propanediol derivatives, key intermediates in our studies on total synthesis of the potent antitumor compound Kazusamycin A are described. After various enzymatic protocols for desymmetrization of t