213754-77-9

Upstream product

• 131311-02-9 (2R,4aR,6S,7R,8aS)-4a,6-Dimethyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 170706-70-4 (2R,4aR,6S,7R,8aS)-7-Benzyloxy-4a,6-dimethyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 170706-73-7 (2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-2-hydroxymethyl-2,6-dimethyl-tetrahydro-pyran-3-ol 
• 170706-71-5 2-((2R,4aR,6S,7R,8aS)-7-Benzyloxy-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-ethanol 
• 170706-72-6 (2R,4aR,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 170706-74-8 (2S,3R,5S,6R)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-5-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2,6-dimethyl-tetrahydro-pyran 
• 100-39-0 benzyl bromide 
• 170706-75-9 [(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-methanol 

Downstream Products

• 170706-78-2 3-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-propionic acid 
• 170706-77-1 3-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-propionic acid methyl ester 
• 170706-83-9 C₅₄H₆₈O₉ 
• 213754-96-2 3-[(2R,4R,4aS,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-4-triisopropylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-propan-1-ol 
• 213754-90-6 [(2S,4R,4aS,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-4-triisopropylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acetic acid methyl ester 
• 213754-92-8 2-[(2R,4R,4aS,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-4-triisopropylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-ethanol 
• 213754-82-6 (E)-(R)-5-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-5-hydroxy-pent-2-enoic acid methyl ester 
• 213754-94-0 [(2R,4R,4aS,6S,7R,8aS)-2-Allyl-7-benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-octahydro-pyrano[3,2-b]pyran-4-yloxy]-triisopropyl-silane 
• 213754-84-8 (E)-(R)-5-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-hydroxy-2,6-dimethyl-tetrahydro-pyran-2-yl]-5-hydroxy-pent-2-enoic acid methyl ester 
• 170706-76-0 (E)-3-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-acrylic acid methyl ester 

Relevant academic research and scientific papers

Total synthesis of brevetoxin B. 1. First generation strategies and new approaches to oxepane systems

The first generation strategies toward the total synthesis of brevetoxin B (1) are presented and the syntheses of the key intermediates 3, 4, 5, 67, 83, and 94-98 required for the projected construction are described. The earliest and most convergent stra