213754-82-6

Upstream product

• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 213754-79-1 (R)-1-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-but-3-en-1-ol 
• 213754-77-9 (2S,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-carbaldehyde 

Downstream Products

• 213754-96-2 3-[(2R,4R,4aS,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-4-triisopropylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-propan-1-ol 
• 213754-90-6 [(2S,4R,4aS,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-4-triisopropylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acetic acid methyl ester 
• 213754-92-8 2-[(2R,4R,4aS,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-4-triisopropylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-ethanol 
• 213754-94-0 [(2R,4R,4aS,6S,7R,8aS)-2-Allyl-7-benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-octahydro-pyrano[3,2-b]pyran-4-yloxy]-triisopropyl-silane 
• 213754-84-8 (E)-(R)-5-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-hydroxy-2,6-dimethyl-tetrahydro-pyran-2-yl]-5-hydroxy-pent-2-enoic acid methyl ester 

Relevant academic research and scientific papers

Synthesis of the AB ring system of gambierol

Synthesis of the AB ring system of gambierol (1) was achieved from 2- deoxy-D-ribose. The key steps were the stereoselective allylation of the aldehyde 6, corresponding to the B ring, and the intramolecular hetero- Michael reaction of 9.