Tetrahedron Letters p. 6365 - 6368 (1998)
Update date:2022-08-04
Topics:
Kadota, Isao
Park, Choul-Hong
Ohtaka, Manabu
Oguro, Nao
Yamamoto, Yoshinori
Synthesis of the AB ring system of gambierol (1) was achieved from 2- deoxy-D-ribose. The key steps were the stereoselective allylation of the aldehyde 6, corresponding to the B ring, and the intramolecular hetero- Michael reaction of 9.
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