213815-24-8

Upstream product

• 250226-98-3 (2R,4S,5R)-4-allyl-2-phenyl-1,3-dioxan-5-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 213815-23-7 (E)-4-[(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-but-2-enoic acid methyl ester 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 193970-21-7 [(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-acetaldehyde 

Downstream Products

• 250226-98-3 (2R,4S,5R)-4-allyl-2-phenyl-1,3-dioxan-5-ol 
• 1032746-03-4 C₁₅H₁₈O₄ 
• 250226-99-4 C₁₅H₂₀O₅ 
• 250227-00-0 C₁₈H₂₂O₆ 
• 250227-02-2 (7S,8R)-7-Benzyloxy-8-benzyloxymethyl-oxocan-2-one 
• 250227-01-1 (6S,7R)-6,8-Bis-benzyloxy-7-hydroxy-octanoic acid 
• 1021700-65-1 C₁₉H₃₀O₄Si 
• 213815-40-8 (2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-7-methyl-2-phenyl-6-triethylsilanyloxymethyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocycloheptene 
• 213815-45-3 tert-Butyl-[(2R,4aR,6S,7R,9aS)-6-((1Z,3Z)-hepta-1,3,6-trienyl)-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-yloxy]-dimethyl-silane 
• 213815-42-0 tert-Butyl-[(2R,4aR,6S,7R,9aS)-6-(2,2-dibromo-vinyl)-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-yloxy]-dimethyl-silane 
• 213815-39-5 (2R,4aR,6S,7R,9aS)-7-Methyl-2-phenyl-6-triethylsilanyloxymethyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213815-34-0 (2R,4aR,6S,7R,9aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213815-43-1 [(2R,4aR,6S,7R,9aS)-6-((Z)-2-Bromo-vinyl)-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-yloxy]-tert-butyl-dimethyl-silane 
• 213815-37-3 (2R,4aR,6S,7R,9aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-ol 

Relevant academic research and scientific papers

Synthetic studies on maitotoxin. 2. Stereoselective synthesis of the WXYZA -ring system

The stereoselective synthesis of the WXYZA -ring system of maitotoxin has been accomplished via a linear synthetic approach, in which key reactions were Sml2-induced cyclization of ss-alkoxyacrylate for the construction of the A -, Y-, and X-rings and 6-endo cyclization of hydroxy vinylepoxide for that of the Z- and W-rings.

A general method for convergent synthesis of polycyclic ethers based on Suzuki cross-coupling: Concise synthesis of the ABCD ring system of ciguatoxin

(matrix presented) A general method for convergent assembly of polyether structure has been developed based on palladium(0)-mediated Suzuki cross-coupling reaction of alkylboranes with cyclic ketene acetal phosphates. The present method allowed for coupli

Synthesis of the H ring of gambierol

Stereoselective synthesis of the H ring of gambierol was achieved from 2-deoxy-D-ribose by using the intramolecular reaction of allylstannane with aldehyde as a key step. Modified Stille coupling was successfully applied for the construction of the triene