213815-28-2

Upstream product

• 106-95-6 allyl bromide 
• 213815-27-1 (2R,4S,5R)-4-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-2-phenyl-[1,3]dioxan-5-ol 
• 193970-21-7 [(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-acetaldehyde 
• 213815-26-0 (2R,4S,5R)-4-(3-Hydroxy-propyl)-2-phenyl-[1,3]dioxan-5-ol 
• 213815-24-8 ((2R,4S,5R)-4-Allyl-2-phenyl-[1,3]dioxan-5-yloxy)-tert-butyl-dimethyl-silane 
• 213815-25-9 3-[(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-propan-1-ol 
• 213815-23-7 (E)-4-[(2R,4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-but-2-enoic acid methyl ester 

Downstream Products

• 213815-40-8 (2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-7-methyl-2-phenyl-6-triethylsilanyloxymethyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocycloheptene 
• 213815-45-3 tert-Butyl-[(2R,4aR,6S,7R,9aS)-6-((1Z,3Z)-hepta-1,3,6-trienyl)-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-yloxy]-dimethyl-silane 
• 213815-42-0 tert-Butyl-[(2R,4aR,6S,7R,9aS)-6-(2,2-dibromo-vinyl)-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-yloxy]-dimethyl-silane 
• 213815-39-5 (2R,4aR,6S,7R,9aS)-7-Methyl-2-phenyl-6-triethylsilanyloxymethyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213815-34-0 (2R,4aR,6S,7R,9aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213815-43-1 [(2R,4aR,6S,7R,9aS)-6-((Z)-2-Bromo-vinyl)-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-yloxy]-tert-butyl-dimethyl-silane 
• 213815-37-3 (2R,4aR,6S,7R,9aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213815-41-9 [(2R,4aR,6S,7R,9aS)-7-(tert-Butyl-dimethyl-silanyloxy)-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-6-yl]-methanol 
• 213815-35-1 (2R,4aR,6S,9aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-2-phenyl-tetrahydro-1,3,5-trioxa-benzocyclohepten-7-one 
• 213815-36-2 (2R,4aR,6S,9aS)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-2-phenyl-4a,9a-dihydro-4H-1,3,5-trioxa-benzocyclohepten-7-one 
• 213815-33-9 (2R,4aR,6S,7R,9aS)-6-Hydroxymethyl-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213815-38-4 (2R,4aR,6S,7R,9aS)-6-Hydroxymethyl-7-methyl-2-phenyl-4a,6,7,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-7-ol 
• 213815-32-8 (2R,4aR,6S,7R,9aS)-2-Phenyl-6-vinyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol 

Relevant academic research and scientific papers

Synthesis of the H ring of gambierol

Stereoselective synthesis of the H ring of gambierol was achieved from 2-deoxy-D-ribose by using the intramolecular reaction of allylstannane with aldehyde as a key step. Modified Stille coupling was successfully applied for the construction of the triene