213824-35-2

Upstream product

• 201142-54-3 (Z)-2-[(2S,3S,4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yloxymethyl]-3-[(1S,2R,6R)-6-isopropyl-3-methyl-2-((2S,3S)-3-methyl-2,3-bis-triethylsilanyloxy-pent-4-ynyl)-cyclohex-3-enyl]-propenal 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 824-94-2 p-methoxybenzyl chloride 
• 193359-93-2 (3aR,6R,7S,7aS)-2,2-Dimethyl-6-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol 
• 201142-49-6 (3R,4R,5S,6R)-5-(4-Methoxy-benzyloxy)-6-phenylsulfanyl-tetrahydro-pyran-3,4-diol 
• 201142-47-4 (3aR,6R,7S,7aR)-7-(4-Methoxy-benzyloxy)-2,2-dimethyl-6-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran 
• 201142-50-9 (2R,3S,4S,5R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2-phenylsulfanyl-tetrahydro-pyran 
• 201142-52-1 2,2,2-Trichloro-acetimidic acid (2S,3S,4S,5R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yl ester 
• 198336-00-4 (1R,5R,6R)-2-[6-(tert-butyldimethylsilanyloxymethyl)-5-isopropyl-2-methylcyclohex-2-enyl]acetaldehyde 
• 201142-29-2 4-[(1R,5R,6R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enyl]-3-hydroxy-butan-2-one 
• 201142-31-6 1-[(1R,5R,6R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-5-isopropyl-2-methyl-cyclohex-2-enyl]-3-methyl-pent-4-yne-2,3-diol 
• 201142-39-4 [(1R,2R,6R)-6-Isopropyl-3-methyl-2-((2S,3S)-3-methyl-2,3-bis-triethylsilanyloxy-pent-4-ynyl)-cyclohex-3-enyl]-methanol 
• 201142-41-8 (1R,2R,6R)-6-Isopropyl-3-methyl-2-((2S,3S)-3-methyl-2,3-bis-triethylsilanyloxy-pent-4-ynyl)-cyclohex-3-enecarbaldehyde 
• 201142-37-2 (4R,5R,6R)-4-Isopropyl-1-methyl-6-((2S,3S)-3-methyl-2,3-bis-triethylsilanyloxy-pent-4-ynyl)-5-triethylsilanyloxymethyl-cyclohexene 

Relevant academic research and scientific papers

Total synthesis of eleutherobin and eleuthosides A and B

The total synthesis of the cytotoxic marine natural products eleutherobin (1) and eleuthosides A (2) and B (3) is described. The strategy involves glycosidation of the (+)-carvone-derived intermediate 7 with the arabinose-derived trichloroacetimidate 9 fo