213826-13-2Relevant academic research and scientific papers
Synthesis of (-)-gleenol via C-H insertion reaction of alkylidenecarbene
Ohira, Susumu,Yoshihara, Naoya,Hasegawa, Taisuke
, p. 739 - 740 (1998)
A spiro sesquiterpene alcohol, (-)-gleenol (1) was synthesized from (-)-1-menthol in 16 steps, using the C-H insertion reaction of the alkylidenecarbene as the key step. The absolute configuration of (-)-1 was determined to be IS, 6R, 7S. 10R.
