Synthesis of (-)-gleenol via C-H insertion reaction of alkylidenecarbene

DOI: 10.1246/cl.1998.739

Source and publish data:

Chemistry Letters p. 739 - 740 (1998)

Update date:2022-08-05

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Authors:

Ohira, Susumu

Yoshihara, Naoya

Hasegawa, Taisuke

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Article abstract of DOI:10.1246/cl.1998.739

A spiro sesquiterpene alcohol, (-)-gleenol (1) was synthesized from (-)-1-menthol in 16 steps, using the C-H insertion reaction of the alkylidenecarbene as the key step. The absolute configuration of (-)-1 was determined to be IS, 6R, 7S. 10R.

Full text of DOI:10.1246/cl.1998.739

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