2140-41-2Relevant academic research and scientific papers
Relative reactivities in the O-methylation of glucomannans: The influence of stereochemistry at C-2 and the solvent effect
Zhang, Yujia,Li, Jiebing,Lindstr?m, Mikael E.,Mischnick, Petra
, p. 172 - 179 (2015/02/19)
The main hemicellulose in softwood, glucomannan (GM), structurally resembles cellulose but has quite different physical and chemical properties. In addition to branching and original acetylation, the only other difference between these two β-1,4-linked gl
Nucleophilic Catalysis of Glycoside Hydrolysis. The Hydrolysis of 4-Nitrophenyl α- and β-D-glucopyranoside Tetraphosphates
Camilleri, Patrick,Jones, Rosie F. D.,Kirby, Anthony J.,Stroemberg, Roger
, p. 2085 - 2090 (2007/10/02)
The octaanion of the tetraphosphate of 4-nitrophenyl β-D-glucopyranoside is hydrolysed up to 100 times faster than model compounds, in a reaction which is pH-independent above pH 9.The mechanism involves intramolecular nucleophilic catalysis by the phosph
