82160-01-8Relevant academic research and scientific papers
Aureolic acid antibiotics: Synthesis of the cyclohexenone segment from D-glucose
Gurjar, M.K.,Devi, T. Rama,Reddy, K.L.N.,Sharma, P.A.,Dhar, T.G. Murali
, p. 995 - 1003 (2007/10/02)
The cyclohexenone segment which is common to all the aureolic acid group of antibiotics has been synthesised from D-glucose.Two routes have been designed to obtain methyl 3-O-benzyl-6-deoxy-2-O-methyl-D-galactopyranoside.Route-A involves the introduction
Aureolic Acid Group of Antibiotics: A Stereospecific Synthesis of Side Chain of Aglycone
Rao, A. V. Rama,Dhar, T. G. Murali,Gujar, M. K.,Yadav, J. S.
, p. 999 - 1000 (2007/10/02)
A stereospecific synthesis of the side chain (4) present in the aureolic acid group of antibiotics, starting from a D-glucose derivative (5) is described.
SYNTHESIS OF 2,3-ANHYDRO- AND 3,4-ANHYDRO-HEXOPYRANOSIDES HAVING A METHYL BRANCH ON THE OXIRANE RING, AND THEIR REACTIONS WITH SOME LITHIUM METHYLCUPRATE REAGENTS
Yoshimura, Juji,Kawauchi, Nobuya,Yasumori, Toshio,Sato, Ken-Ichi,Hashimoto, Hironobu
, p. 255 - 274 (2007/10/02)
Three 2,3-anhydroaldohexopyranosides having a 2-C-methyl or 3-C-methyl branch, as well as three 3,4-anhydroaldohexopyranosides having a 3-C-methyl (7) or 4-C-methyl branch, were newly synthesized.The reactions of these, together with those of a known 3-C-
STEREOSELETIVITIES IN THE REACTIONS OF α-D-HEXOPYRANOSID-4-ULOSES WITH DIAZOMETHANE
Sato, Ken-Ichi,Yoshimura, Juji
, p. 221 - 238 (2007/10/02)
The stetreoselectivities in the reactions of diazomethane with various α-D-hexopyranosid-4-uloses are compared with those in Grignard reactions.The results support the hypothesis that the stereoselectivity of the diazomethane reaction is mainly controlled
