109280-61-7

Upstream product

• 100-39-0 benzyl bromide 
• 110715-30-5 methyl 4,6-O-benzylidene-2-O-methyl-β-D-glucopyranoside 
• 129706-93-0 methyl 3-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 74-88-4 methyl iodide 
• 110594-89-3 3,4,6-tri-O-acetyl-2-O-methyl-1-deoxy-1-piperidino-β-D-glucose 
• 81024-47-7 methyl 2-O-methylglucopyraniside 
• 2140-41-2 2-O-methyl-D-glucopyranose 

Downstream Products

• 71695-51-7 methyl 3-O-benzyl-6-deoxy-2-O-methyl-α-D-glucopyranoside 
• 110594-92-8 methyl 3-O-benzyl-6-deoxy-2-O-methyl-β-D-glucopyranoside 
• 82160-01-8 (2R,4R,5R,6R)-4-Benzyloxy-5,6-dimethoxy-2-methyl-dihydro-pyran-3-one 
• 110594-93-9 Methanesulfonic acid (2R,3R,4R,5R,6R)-4-benzyloxy-2-methanesulfonyloxymethyl-5,6-dimethoxy-tetrahydro-pyran-3-yl ester 
• 109200-91-1 2-O-methyl-3-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

The influence of neighboring group participation on the hydrolysis of 2-O-substituted methyl glucopyranosides

Does neighboring group participation actually enhance the reactivity of the anomeric center when the participating group is inherently disarming? To investigate the influence of the neighboring group effect from a 2-O protective group on acidic glycoside hydrolysis, 10 methyl glucosides having different protective groups on O2 have been synthesized and a clear trend between anomeric configuration, participation of the protective group, and the rate of hydrolysis could be observed.

Aureolic Acid Group of Antibiotics: A Stereospecific Synthesis of Side Chain of Aglycone

A stereospecific synthesis of the side chain (4) present in the aureolic acid group of antibiotics, starting from a D-glucose derivative (5) is described.