214077-01-7Relevant articles and documents
Investigation of Mn(III)-based oxidative free radical cyclization reactions toward the synthesis of triptolide: The effects of lanthanide triflates and substituents on stereoselectivity
Yang, Dan,Ye, Xiang-Yang,Xu, Ming,Pang, Kwan-Wah,Cheung, Kung-Kai
, p. 1658 - 1663 (2007/10/03)
Mn(III)-mediated oxidative free radical cyclization reactions are useful for construction of polycyclic compounds. In the total synthesis of triptolide (3) and its related compounds, construction of tricyclic skeletons 4 and 5 was achieved by the Mn(OAc)