214333-70-7

Basic information

• Product Name: 2-oxopropyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside
• Synonyms: 2-oxopropyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside
• CAS NO: 214333-70-7
• Molecular Weight: 596.72
• Mol File: 214333-70-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-oxopropyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 2-oxopropyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside(214333-70-7)
• EPA Substance Registry System: 2-oxopropyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside(214333-70-7)

Safety Data

• Hazardous Substances Data: 214333-70-7(Hazardous Substances Data)

Upstream product

• 34272-03-2 propargyl β-D-glucopyranoside 
• 604-69-3 β-D-glucose pentaacetate 
• 100-39-0 benzyl bromide 
• 194088-16-9 1-O-propargyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 34272-02-1 1-O-propargyl 2,3,4,6-tetra-O-acetyl-β-D-glucose 
• 194088-15-8 allenyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 

Downstream Products

• 214333-67-2 (2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)methylene acetate 
• 367946-92-7 tert-butyl 2,3,4,6-tetra-O-benzyl-α,β-D-glucopyranoside 
• 6207-45-0 2-(allyloxy)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)-tetrahydro-2H-pyran 
• 61474-61-1 methyl 2,3,4-tri-O-benzyl-6-O-(2,3,4,6-tetra-O-benzyl-D-glucopyranosyl)-α-D-glucopyranoside 
• 84799-76-8 methyl O-(2,3,4,6-tetra-O-benzyl-D-glucopyranosyl)-(1-4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

Study of metal and acid catalysed deprotection of propargyl ethers of alcohols via their allenyl ethers

A new method for the deprotection of prop-2-ynyl ethers 1b-9b is described. Isomerisation of 1b-9b to O-allenyl ethers 1d-9d and deprotection by reaction with Hg(OCOCF3)2, aq.HCl, aq.CF3CO2H and best by use of a catalytic amount of OsO4 is described to obtain the alcohols 1a-9a in good yield. Application of this method for the deprotection of prop-2-enyl ethers 7c,8c,10c-13c via their corresponding prop-1-enyl ethers 7e,8e,10e-13e to obtain the corresponding alcohols 7a,8a,10a-13a is also described.