214360-58-4

Basic information

• Product Name: 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FLUOROBENZENE
• Synonyms: 2-(4-Fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;4-Fluorobenzeneboronic acid, pinacol ester;1,3,2-Dioxaborolane,2-(4-fluorophenyl)-4,4,5,5-tetraMethyl-;4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)fluorobenzene 214360-58-4;SWZn-214360-58-4;4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FLUOROBENZENE;4-FLUOROPHENYLBORONIC ACID, PINACOL ESTER;4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-FLUOROBENZENE 90%
• CAS NO: 214360-58-4
• Molecular Formula: C₁₂H₁₆BFO₂
• Molecular Weight: 222.06
• EINECS: 671-855-0
• Product Categories: Heterocyclic Compounds
• Mol File: 214360-58-4.mol
• Article Data: 123

Chemical Properties

• Boiling Point: 279.4°Cat760mmHg
• Flash Point: 122.8°C
• Appearance: /
• Density: 1.05g/cm³
• Vapor Pressure: 0.00684mmHg at 25°C
• Refractive Index: 1.479
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• CAS DataBase Reference: 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FLUOROBENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FLUOROBENZENE(214360-58-4)
• EPA Substance Registry System: 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FLUOROBENZENE(214360-58-4)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 214360-58-4(Hazardous Substances Data)

Usage

General Description

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)fluorobenzene is a specialized chemical compound used in a variety of research and scientific contexts. As an organoboron compound, it has properties that make it useful in areas such as the synthesis of complex organic molecules, including pharmaceuticals. Its structure contains a fluorobenzene ring, which is coupled to a tetramethyl boron group. The latter contains the boron atom, crucial for many chemical reactions, including Suzuki coupling. Despite its complex structure, it's typically available as a commercial product from various suppliers for use in laboratory contexts.

InChI:InChI=1/C12H16BFO2/c1-11(2)12(3,4)16-13(15-11)9-5-7-10(14)8-6-9/h5-8H,1-4H3

Upstream product

• 352-33-0 1-Chloro-4-fluorobenzene 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 61676-62-8 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 1765-93-1 4-fluoroboronic acid 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 371-40-4 4-fluoroaniline 
• 352-34-1 4-fluoro-1-iodobenzene 
• 78782-17-9 4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane 
• 73183-34-3 bis(pinacol)diborane 
• 1268613-26-8 4-fluorophenylboronic acid catechol ester 
• 403-46-3 4-fluoro-N,N-dimethylaniline 
• 823-85-8 4-fluorophenyhydrazine hydrochloride 

Downstream Products

• 99770-93-1 benzene-1,4-diboronic acid bispinacol ester 
• 1103930-19-3 methyl 4-(2-(2-(4-benzhydrylpiperazin-1-yl)-2-oxoethoxy)acetamido)-4'-fluorobiphenyl-3-carboxylate 
• 1103930-74-0 methyl 4-(2-(2-(benzhydrylamino)-2-oxoethoxy)acetamido)-4'-fluorobiphenyl-3-carboxylate 
• 1187951-65-0 C₂₃H₁₈FN₃O₂S 
• 1187951-69-4 C₂₄H₂₀FN₃O₂S 
• 324-74-3 4-fluoro-biphenyl 
• 1351476-56-6 C₂₅H₂₅FN₄ 
• 1351477-61-6 C₃₂H₃₁FN₄O₂S 
• 398-24-3 4-fluoro-4'-nitro-1,1'-biphenyl 
• 1373773-68-2 2,5-bis[5’-(4-fluorophenyl)-3’-hexylthiophen-2’-yl]-thiazolo[5,4-d]thiazole 
• 58656-98-7 tert-butyl 4-fluorobenzoate 
• 658-75-3 p-fluorophenyl trifluoroacetate 
• 1194-02-1 4-fluorobenzonitrile 

Relevant articles and documents

Cu-mediated: vs. Cu-free selective borylation of aryl alkyl sulfones

A Cu-catalysed borylation of aryl alkyl sulfones was developed for the high yield synthesis of versatile arylboronic esters using a readily prepared NHC-Cu catalyst. In addition, the selective cleavage of either alkyl(C)-sulfonyl or aryl(C)-sulfonyl bonds

Unreactive C-N Bond Activation of Anilines via Photoinduced Aerobic Borylation

Unreactive C-N bond activation of anilines was achieved by photoinduced aerobic borylation. A diverse range of tertiary and secondary anilines were converted to aryl boronate esters in moderate to good yields with wide functional group tolerance under simple and ambient photochemical conditions. This transformation achieved the direct and facile C-N bond activation of unreactive anilines, providing a convenient and practical route transforming widely available anilines into useful aryl boronate esters.

Organic compound, and organic electroluminescent device and electronic device using same

The invention relates to an organic compound. The structure of the organic compound comprises a formula I. When the organic compound provided by the invention is used for a light-emitting layer of anorganic electroluminescent device, the device efficiency of the device can be effectively improved, and the service life of the organic electroluminescent device is prolonged.