214399-71-0

Basic information

• Product Name: [RuCp(PPh₃)(PPr(i)2Me)(Cl)]
• CAS NO: 214399-71-0
• Molecular Weight: 596.094
• Mol File: 214399-71-0.mol

Chemical Properties

• CAS DataBase Reference: [RuCp(PPh₃)(PPr(i)2Me)(Cl)](CAS DataBase Reference)
• NIST Chemistry Reference: [RuCp(PPh₃)(PPr(i)2Me)(Cl)](214399-71-0)
• EPA Substance Registry System: [RuCp(PPh₃)(PPr(i)2Me)(Cl)](214399-71-0)

Safety Data

• Hazardous Substances Data: 214399-71-0(Hazardous Substances Data)

Upstream product

• 32993-05-8 chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) 
• 60054-88-8 diisopropylmethylphosphine 

Downstream Products

• 214399-83-4 (C₅H₅)Ru(P(C₆H₅)3)(P(CH(CH₃)2)2CH₃)(SC₅H₅N)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(C₅H₅)Ru(P(C₆H₅)3)(P(CH(CH₃)2)2CH₃)(SC₅H₅N)][B(C₆H₅)4] 
• 406187-97-1 C₅H₅Ru(PCH₃(C₃H₇)2)P(C₆H₅)3N₂⁽¹⁺⁾*B((CF₃)2C₆H₃)4^(1-)=C₅H₅Ru(PCH₃(C₃H₇)2)P(C₆H₅)3N₂(B((CF₃)2C₆H₃)4) 
• 406188-03-2 [CpRu(PMe(iPr)2)(η3-PPh3)][B(C6H3-(CF3)2-3,5)4] 
• 317373-72-1 [RuCp(PPh₃)(PPr(i)2Me)(H)] 

Relevant articles and documents

Unexpected effect of the ring on the extent of Si...H interligand interactions in half-sandwich silyl hydrides of ruthenium

This paper reports preparation of new silyl hydride complexes of ruthenium supported by the Cp/PR3 ligand set. It is shown that the easiest and most general route to these complexes is provided by the thermal reaction of [RuCp(PR3)(H

Half-sandwich ruthenium phosphine complexes with sulfur-donor ligands. X-ray crystal structures of [Cp*RuH(SH)(PEt3)2][BPh4] and [Cp*Ru(S2COiPr)(PEt3)]

The complexes [CpRuCl(PEt3)2 (1) and [CpRuCl(PMeiPr2)(PPh3)] (2) react with H2S in EtOH in the presence of NaBPh4 furnishing the green persulfide derivatives [{CpRu(L)}2/su