214627-66-4Relevant articles and documents
Cp*IrIII-Catalyzed [3+2] Annulations of N-Aryl-2-aminopyrimidines with Sulfoxonium Ylides to Access 2-Alkyl Indoles Through C–H Bond Activation
Luo, Yi,Guo, Lingmei,Yu, Xinling,Ding, Haosheng,Wang, Huijing,Wu, Yong
supporting information, p. 3203 - 3207 (2019/06/08)
The iridium-catalyzed aromatic C–H alkylation followed by intramolecular annulation reactions between N-aryl-2-aminopyridines and sulfoxonium ylides for the synthesis of 2-alkyl indoles is described. This highly efficient and step-economical cyclization r
A copper-mediated tandem reaction through isocyanide insertion into N-H bonds: Efficient access to unsymmetrical tetrasubstituted ureas
Huang, Xiaomei,Xu, Shuguang,Tan, Qitao,Gao, Mingchun,Li, Minjie,Xu, Bin
supporting information, p. 1465 - 1468 (2014/02/14)
A copper-mediated multi-component reaction was developed through isocyanide insertion into N-H bonds of less active secondary arylamines. This approach leads to an efficient synthesis of unsymmetrical tetrasubstituted ureas in one pot. The Royal Society of Chemistry.
Zinc base assisted amination of 2-chloropyrimidines by aniline derivatives at room temperature
Delvos, Lukas B.,Begouin, Jeanne-Marie,Gosmini, Corinne
supporting information; experimental part, p. 2325 - 2328 (2011/11/06)
The amination of 2-chloropyrimidines was performed with several aniline derivatives in the presence of tolylzinc bromide as a base. The organozinc compound has a profound effect on the reactivity of the amines, so that the reaction takes place at room tem
